Questions tagged [precipitation]
For questions related to the chemical reactions and processes that result in a chemical reaching its solid phase.
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Why is the Ag+ concentration in a beaker fixed in the reaction between excess AgCl (s) and KI (aq) from the start? [duplicate]
This arises as a sub-question for the following question: Calculate the concentration of I- in a solution obtained by mixing 0.10 M KI with an excess of AgCl(s).
I tried to look at How does addition ...
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Calculate the concentration of I− in a solution obtained by shaking 0.10 M KI with an excess of AgCl(s) [duplicate]
My textbook says to solve it in the following way:
1) Ignore the $\pu{0.10 M}$ $\ce{KI}$ since it doesn't matter.
2) Since you have excess $\ce{AgCl(s)}$, you can calculate the $\ce{Ag+}$ ...
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Adding aluminum sulfate to neutralize an aqueous solution of sodium silicate with pH of 12.6
How much aluminum sulfate do I need to add to an aqueous solution of sodium silicate to neutralize the solution (pH from 12.6 to 7)?
For a water treatment school project, we remove sodium silicate ...
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Why is hydrated barium peroxide used in the preparation of hydrogen peroxide?
I read about the laboratory method of producing hydrogen peroxide. The chemical reaction in question is: $$\text{BaO}_2.8\text{H}_2\text{O} + \text{H}_2\text{SO}_4 \rightarrow \text{BaSO}_4+\text{H}_2\...
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1answer
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Si(OH)4 vs. H4SiO4 vs. SiO2.2H2O
Can someone please explain to me what is the differences between $\ce{Si(OH)4}$, $\ce{H4SiO4}$, and $\ce{SiO2.2H2O}$? I am currently studying sandstone acidizing geochemical models and this question ...
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Can I extract solid sugar from any fruit juice at home?
The goal here is to isolate the sugar from all other compounds in the juice. In this case, I'm using apple juice and grape juice. The sugar does not need to be edible, as it is being used to make r-...
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1answer
48 views
Precipitation of a lead(II) sulfate
Lead (II) sulfate precipitate can be dissolved if:
a) We add an acid
b) We add EDTA
c) None of the above is true.
I think EDTA is a ligand, and if you want to dissolve the sulfate, then Pb sticks ...
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2answers
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Why do reusable heat packs have a limited time frame before the reaction becomes irreversible?
I have two "rechargeable" heat packs which from my understanding operate on the phase change
$$ CH_3COONa_{(aq)} \rightleftharpoons CH_3COONa_{(s)} + \Delta H.$$
Triggering the ...
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3answers
565 views
Can precipitation occur in states of matter other than liquids?
This answer to Are precipitation and crystallization both analogous between chemistry and meteorology? discusses the history and use of the term "precipitation" in chemistry.
From what I ...
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Are precipitation and crystallization both analogous between Chemistry and Meteorology?
A comment under the Space SE question Is there really precipitation on Mars? Does frost count? brings up the use of the term "precipitation" in chemistry and we wonder if precipitation in ...
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Reaction of Glucose + NaOH + PVP
I'm trying to synthesize of silver particles by using glucose as reducing agent, PVP as dispersant, and NaOH as pH control. Before adding silver nitrate solution, I've produced a solution which is ...
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3answers
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A problem regarding solubility and concentration
A solution is $\pu{0.10 M}$ $\ce{Ba(NO3)2}$ and $\pu{0.10 M}$ $\ce{Sr(NO3)2}$. If solid $\ce{Na2CrO4}$ is added to the solution, what is the $\ce{[Ba+]}$ when $\ce{SrCrO4}$ begins to precipitate? $\...
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1answer
59 views
Co-precipitation particle size
If we are creating a precipitate of (say) Barium Sulfate from a solution of Barium Chloride mixed with Sodium Sulfate, what determines the particle size?
I assume one of the factors will be ...
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Preventing Precipitation/Undilution: Shall I Try Another Solvent?
Thank you for your time in advance.
Our facility is about $\pu{4000 ft}$ in terms of elevation.
One of the main chemicals we manufacture is RAD140 or $\ce{C20H16ClN5O2}$.
We use DMSO ($\ce{(CH3)2SO}$),...
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Solubility Product, and it's relation to solubility
In order to remove temporary hardness of water, it is boiled.
On boiling, while Ca(HCO3)2 gives CaCo3(ppt.) , Mg(HCO3)2 gives Mg(OH)2(ppt.).
According to my book precipitation of Mg(OH)2 occurs due to ...
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1answer
191 views
Why is the test for sodium as dihydrogen antimonate so specific?
I have been attending lectures of salt analysis in my college. We are at group 6 cations or also known as group zero cations, namely $\ce{NH4^+}$, $\ce{K^+}$, $\ce{Na^+}$, $\ce{Mg^2+}$.
The lecturer ...
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Free Energy vs. Common Ion Effect in Ultrapurification
I'm wondering which of the two phenomenae grows in importance and which one becomes irrelevant when the proportion of impurities in a product being purified become increasingly small:
The common ion ...
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Material properties differing between vacuum or pressure filtration
During vacuum filtration of a very fine suspension, all solids that need to be removed are, but there is minimal solids loss. If the same material is pressure filtered (1-2 bar), desired solids ...
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2answers
60 views
Seperating out iron from ferrous sulfate
I don't need to necessarily seperate pure iron, but from a ferrous sulfate solution, I am trying to form a precipitate with iron. By getting a precipitation of an iron compound, I can find out the ...
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4answers
167 views
How many grams of sodium phosphate must be added to precipitate as much of one ion as possible?
Problem text:
Solid sodium phosphate is slowly added to $\pu{200 mL}$ of a solution containing $\pu{0.002 mol}$ of aluminum chloride and $\pu{0.001 mol}$ of calcium chloride (assuming no volume ...
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1answer
174 views
Using solubility product to determine the mass of the precipitate of a reaction
I mix together $\pu{100 mL}$ of an aqueous $\ce{NaCl}$ solution at $\pu{0.5 M}$ and $\pu{100 mL}$ of an aqueous $\ce{AgNO3}$ solution at $\pu{0.3 M}$. Assuming that the solubility of $\ce{NaCl}$ in ...
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Which salts precipitate from a potassium/sodium chloride/sulfate solution?
This is not a homework question. I am not in any course of study. The following question arises from my personal curiosity. If 1 mole of sodium sulfate and 2 moles of potassium chloride are dissolved ...
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Why does silver stick to the glass in Tollens' test? [duplicate]
Why does it not simply form a solid powder at the bottom of the flask?
Does silver also stick to the glass in other silver precipitating reactions?
EDIT:
My question is definitely not the same as ...
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1answer
72 views
Qualitative Analysis- Distinguishing between two ions or two salts [duplicate]
I know my question is going to be quite below the level of this site but I am 1st grade in university and I can't understand anything.
I am going to give an example from the book: distinguish ...
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2answers
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How can I dissolve a precipitate when stuck to the side of a boiling flask
I’ve been experimenting with producing Iron Acetates and I’ve run into a snag. Here’s my process so far:
I started by adding white vinegar and ~50% Hydrogen Peroxide to a reaction vessel with steel ...
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1answer
34 views
Solutions and Precipitates [closed]
If a solution of $\pu{20mL}$ of $\pu{ 0.050M}~\ce{K+ }$is added to $\pu{80mL}$ of
$\pu{0.50M}\ce{ClO4-}$ will a precipitate form and what is the value of $Q_\mathrm{sp}$? For $\ce{KClO4}, K_\mathrm{...
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Will calcium concentrations be reduced when water is boiled at lower atmospheric pressure? [closed]
It's well documented that one can reduce calcium concentrations in water by boiling the water. This is caused by CO2 being driven out of the water and the calcium precipitating out of solution. Ok, ...
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271 views
DIY hand sanitiser solution forms spongy substance
I am trying to make my own hand sanitiser since it’s sold out everywhere. The formula I use is 1 part aloe vera gel in 2 parts 100% isopropyl alcohol. The problem is when mixing the two, the solution ...
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Remove carbon dioxide from solution [closed]
What solution could I add to a solution of water with dissolved carbon dioxide in order to get the carbon to precipitate out? I believe the ions are H+ and HCO3-
Thanks, Jerid
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Is the kinetic energy change of a system (q) equal to the enthalpy change of a system (∆H)?
When silver nitrate and hydrochloric acid are put together in a container, they form silver chloride. If you're given information about the reactants (including temperature change, heat capacity, and ...
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1answer
96 views
How to precipitate Chloroplatinic acid? [closed]
For the precipitation reaction, I have to react $\ce{H2PtCl6}$ with $\ce{(NH4)2CO3}$ while maintaining the $\ce{pH}$ in the range of 7-8 at 60 °C. But the problem is Chloroplatinic acid is not ...
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1answer
33 views
Effect of reduction potential on particle size of chemically precipitated silver particles [duplicate]
Is there no mathematical relationship between redox potential and particle size saying that an $X$ potential should yield a $Y$ particle size? Right now its general that large redox potential results ...
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1answer
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Is there a name, or any specific jargon for a precipitation equilibrium involving a solid reactant?
Let's say you have some ions in solution, for example Na+(aq) and OH-(aq), and some partially dissolved solid, MgCO3(s), Mg+2(aq) and CO3-2(aq), which precipitates Mg(OH)2(s) until equilibrium.
So ...
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2answers
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Will NaF + CaCO3 precipitate much CaF2?
If I mix sodium fluoride, calcium carbonate powder, and water, under what conditions (if any) would there be an equilibrium?
I.e. assume we start out with fully dissociated $\ce{Na+(aq) + F-(aq)}$, ...
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Ideal characterization technique to study behavior of heated metal nitrates
I have 3-4 metal nitrates as precursors for my coprecipitation reaction. I need to study the behavior of each individual nitrate and also of various combinations at 60 degrees Celsius, which is my ...
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Does brewing tea with hard water reduce the amount of bioavailable fluorine?
I read that brewed tea contains a relatively large concentration of Fluorine.
Fluorine can have negative health effects such as Skeletal Fluorosis. EDIT: I understand some Fluorine is necessary and ...
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2answers
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Preparation of Barium Hexaaluminate using co-precipitation reaction mechanism
I am preparing Barium Hexaaluminate (BHA) using $\ce{Ba(NO3)2, Al(NO3)3}$, and $\ce{(NH4)2CO3}$. For $\pu{1 mol}$ of each $\ce{Ba(NO3)2}$ and $\ce{Al(NO3)4}$, I am using $\pu{1.5 mol}$ of $\ce{(NH4)...
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1answer
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How to calculate the amount of sodium sulfate needed to lower the silver ion concentration of a saturated silver sulfate solution?
How many moles of $\ce{Na2SO4}$ we have to add into a saturated $\pu{0.5 L}$ solution of $\ce{Ag2SO4}$ so that the concentration of $\ce{Ag}$ is $\pu{4.0 \times 10^-3 M}$? ($K_\mathrm{sp} = 1.4 \times ...
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2answers
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Calculating equilibrium concentrations of silver and halide ions
$\pu{500 ml}$ of $\pu{0.01 M}$ $\ce{AgNO3}$ is mixed with $\pu{500 ml}$ of solution containing $\pu{0.1 M}$ $\ce{NaCl}$ and $\pu{0.1 M}$ $\ce{NaBr}$. $K_\mathrm{sp}$ of $\ce{AgCl}$ is $10^{-10}$ and $...
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1answer
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Is chromate a suitable indicator for the titration of Ag⁺ with Cl⁻?
To titrate $\ce{Cl-}$ with $\ce{Ag+}$ we use chromate $\ce{CrO4^2-}$ as an indicator.
The titration reaction is:
$$\ce{Ag+ + Cl- <=> AgCl}\tag{R1}$$
$$K_1 = \frac{1}{K_\mathrm{sp}(\ce{AgCl})} =...
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Method to find out the amount of solvent replaced by another solvent
So I am performing a relatively simple coprecipitation experiment to synthesize ceramics. All my precursors are in aqueous solutions. But due to the high surface tension of water, drying the water is ...
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1answer
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Selectivity of metal nitrates towards ammonium bicarbonate
I am performing coprecipitation reaction, and in the precipitating step, I have a bunch of metal nitrates(ferric nitrate, aluminium nitrate and barium nitrate)in a solution reacting with ammonium ...
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1answer
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Precipitation of water-insoluble materials from shower or laundry greywater
I am currently working on a project to build a filter that aims to separate or salt out the 'dirt' in shower or laundry greywater. The ideal result from this chemical reaction will be such that the '...
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2answers
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Predicting a precipitate based on Ksp
$\pu{105 mL}$ of $\pu{0.10 M}$ $\ce{AgNO3}$ is added to $\pu{125 mL}$ of $\pu{0.35 M}$ $\ce{K2CrO4}.$ Will a precipitate form? $(K_\mathrm{sp}$ for $\ce{Ag2CrO4}$ is $\pu{1.12E-12}.)$
Answer:
Can ...
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3answers
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How do Precipitation Reactions behave in the Absence of Gravity?
How do precipitation reactions behave in the absence of gravity, say on the International Space Station (ISS)? I have seen water taking the shape of a sphere and not that of the container in space due ...
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Can classification techniques used for identifying solids be used to identify precipitates?
I am preparing for an assessed practical experiment where an unknown precipitate must be identified. I know that precipitates are insoluble, and my textbook says they are considered to be solid with ...
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Using a weak acid to prevent the precipitation of Mg(OH)2
I have this exercise in my chemistry book, and I have been staring at it for so long but unfortunately I have no single idea what to do and where to start. I will be so thankful for any help.
$0.05$ ...
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1answer
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Why is only the carbonate anion used to precipitate Barium?
Q: Why is the $\ce{CO3^2-}$ anion used to precipitate Barium from $\ce{BaBr2}$ and not another anion, such as $\ce{PO4^3-}$, or $\ce{SO4^2-}$?
I am studying high school Chemistry, and the current ...
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1answer
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Which metal ions precipitate in NH4OH? [closed]
From Wikipedia-1, and from an answer here on Stack-Exchange, I can list at least the following elements which will dissolve in aqueous $\ce{NH4OH}$:
$\ce{Cr(III), Co(III), Ni(II), Cu(I, II), Zn(II), ...
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2answers
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Which salts can be used to precipitate chloride ions? [closed]
We don’t have AgNO3 in the lab. I have no idea what else can be useful.
I am washing a product and I want to make sure the chlorides are washed away.
