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Questions tagged [metal]

For questions about metals in general and their physical or chemical properties. For characteristic properties and reactions of d and f block metals specifically, use the [transition-metals] and [rare-earth-elements] tags respectively instead.

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24 views

Why are colloidal solutions of metals negatively charged?

Colloidal solutions of metals are negatively charged. The charge on the sol particles is due to electron capture by sol particles during electro-dispersion of metals. Electro dispersion involves ...
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3answers
2k views

How can steel be so different from iron, even if amount of carbon is small?

Perhaps I am too naive, but I am having a hard time visualizing how even 'high-carbon' iron and steel alloys are maybe, at most, about four percent carbon by mass, which still means only one (smaller) ...
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24 views

Natural preservatives of ink

Would pure compounds like thymol, carvacrol and cinnamaldehyde work as preservatives of fountain pen ink? I'm specifically interested in three properties - Prevention of growth (mostly fungal) in the ...
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0answers
77 views

How is this Clemmensen Reduction taking place? [closed]

How did that isotopically labelled Carbon migrate? I know that an carbanion is formed, but I am not able to conclude the final product. Please Help
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0answers
30 views

Lithium Air vs Li Fluoride battery capacity [closed]

Lithium air aka lithium oxygen batteries are described as highest theoretical capacity battery possible. In wikipedia, it says lithium air has energy density 5210 Watt hour per kg, including weight of ...
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0answers
41 views

Metal oxide formation minimum temperature?

Is there such thing as minimum temperature for creation of metal oxide? Let's say a highly reactive metal, lithium, comes into contact with solid oxygen at a cryogenic temperature of 20 Kelvin, would ...
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2answers
65 views

Extraction of copper from chalcopyrite

During the extraction of copper from chalcopyrite ore, the ore ($\ce{Cu2S.Fe2S3}$) is heated to form $\ce{Cu2S}$ and $\ce{FeS}$. Then during smelting it reacts with $\ce{O2}$ to form $\ce{Cu2O}$. Then ...
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why do anode sludge form in copper purification

when I research on copper purification, it is often stated that impurities with lower E° value will discharge before copper but simply "not dissolve and fall to the bottom"(example at 2:55), ...
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4answers
1k views

Can a metal be forced to form an anion theoretically? [duplicate]

I know that metals have the capability to lose electrons and form cations, but is it also theoretically possible to supply an electron to a metal so that it forms an anion? If so, has it ever been ...
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2answers
104 views

Upon the addition of metallic sodium to cold water, is an explosion possible?

In a Cambridge IGCSE question paper, the following question was asked: Describe the reaction of sodium with cold water. Include the observations that can be made. I was thinking of writing that &...
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53 views

Why is it that not all metals produce hydroxides when reacting with water? [duplicate]

I was taught, as a rule, that: metals + water $\rightarrow$ metal hydroxide + hydrogen gas $$\text{Na} + \text{H}_2\text{O} \rightarrow \text{NaOH} + \text{H}_2$$ However: $$3\text{Fe} + 4\text{H}...
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1answer
118 views

Ferrous chloride solution coming out purple rather than green?

I've got some steel wool in hydrochloric acid to attempt to make ferrous chloride and the whole solution has turned purple. From everything I've seen it's supposed to be green. I have no idea what's ...
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1answer
121 views

Why is the term "nascent nitrogen" still used in metallurgical industries?

Continuation of Why do nitrogen-containing organic compounds give N2 as the combustion product? (comment converted into question) Nascent state is an obsolete theory in chemistry and is discredited. ...
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44 views

Corrosive potential of molten ionic salt

I was looking at this video about fourth generation of nuclear reactors and one of developing concepts is molten salt reactor (MSR) where melted ionic salt replaces water as coolant and also acts as a ...
5
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2answers
421 views

Is there a simple way to distinguish grades of purity for copper metal?

Is there a simple way to distinguish different grades of fine copper purity (on a trace metal basis) that can be carried out in a small lab? Specifically, I would like to be able to differentiate 4N, ...
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0answers
67 views

I have tried to remove oxidation from a metal scraper using vinegar, now the metal looks and smells burnt, what went wrong?

I have recently tried to remove some oxidation from a metal scraper spatula by using vinegar. After leaving it there for a couple of hours I was left with a burnt smell (with a hint of burnt candle ...
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2answers
40 views

What is the cathode in NiMH batteries

What is the cathode in $\ce{NiMH}$ batteries? I’m not sure if it is $\ce{Ni(OH)2}$ or $\ce{NiOOH}$. I’m confused because I thought that these batteries are like $\ce{NiCd}$ batteries except better (...
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1answer
116 views

What is/was "uraneous oxide"? Was it an accepted name for a compound or mixed oxides of uranium?

In This National Technical Reports Library page for a 1965 report Method for Coating Actinide Particles in the list of keywords both Uranium compounds and Uraneous oxide are listed. But I don't find ...
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0answers
36 views

Passivation of metals in acids

It is commonly taught in chemistry textbooks that metals such as $\ce{Fe, Al, Cr}$ is "passivated" in cold concentrated $\ce{H2SO4}$ and $\ce{HNO3}$ due to them forming oxide films on the ...
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0answers
18 views

How can the difference between surface energy and electrostatic repulsion be calculated in electroplating?

When metals are electroplated unto surfaces, there are a myriad of forces at play. To set a clear example, if one were to electroplate a magnet with a diamagnetic metal such as bismuth, there will be ...
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1answer
59 views

What is the alloying composition of the Zinc-Platinum System?

My research team and I are working on a bimetallic alloy consisting of Zinc and Platinum. We have looked for papers regarding the composition of Zinc-Platinum alloy. But there aren't many papers out ...
5
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1answer
161 views

Boiling sodium hydroxide in stainless steel cup: Solution turning to a blue color

I boiled highly concentrated sodium hydroxide in a stainless steel cup. This created a blackish layer on the bottom of the cup and turned the colour of the sodium hydroxide solution to blueish. Am I ...
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1answer
2k views

Why do only some metals make protective oxide layers?

Almost all Alkali metals and Alkaline Earth metals react with air to form their respective oxides, but why does only Magnesium forms a protective oxide layer? What properties of magnesium oxide allow ...
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0answers
39 views

Avoiding chemical reactions with carbonated alcoholic drinks

I'm making a cooling beverage dispenser for carbonated drinks. The keg remains room temperature and the beverage rises through a pipe that's coiled up inside a cooling unit filled with water or ...
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1answer
39 views

What happens to vaporized metal in the atmosphere when it cools down? [closed]

Imagine you vaporize a chunk of metal like an iron meteorite or plutonium or whatever in the atmosphere. What happens to that metal when it cools down? Does it form dust and drop in the nearby ...
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2answers
119 views

Will a titanium piercing tarnish if submerged in sulfur water (hot spring)?

I have tried to research whether titanium piercings will tarnish if one submerges in sulfur hot springs. Will titanium piercings react to the sulfur water?
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15 views

How can I wet etch Nickel Chloride (NiCl/NiCl2) off a GaN sample

Apologies in advance for what may be a basic chemistry question - I'm asking from the point of view of microlithography. I have a Gallium Nitride sample which I have etched in a Ar/Cl plasma with a ...
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1answer
230 views

Why does the cathode in an OLED require a low work function and the anode require a high work function?

I am currently doing some research on organic light emitting diodes and am just trying to get my head around some of the terminology and concepts because I am more from the organic chemistry side don'...
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0answers
29 views

Standard practice for keeping salts dry

I should point out first that I'm not a chemist, but I'm currently doing a little bit of chemistry; this should clarify that I don't have formal training in a chemistry lab (other than some basic chem ...
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2answers
356 views

How to refine manganese metal from manganese(IV) oxide found in batteries? [closed]

I opened up some lantern batteries, and inside there's $\ce{MnO2}$ powder, carbon rods, and zinc casings, and other stuff that I don't know what it is exactly. I scraped out $\ce{MnO2}$-containing ...
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1answer
91 views

Thinking of reducing aluminum hydroxide with magnesium

Is it possible to reduce aluminum hydroxide to aluminum metal by using a sacrificial magnesium electrode in a single displacement reaction? I checked my revision of redox charts and it looks like it ...
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0answers
65 views

Wittig reagent with metal–oxo bonds

Could you use the Wittig reagent to attack a metal–oxo bond and replace the oxygen with a carbene? Specifically, is it possible for the Wittig reagent to do σ-bond metathesis with an electrophilic ...
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1answer
44 views

When Iron reacts with any other species, how will we know that the reaction will be of Fe(II) or Fe(III) i.e. of ferrous or ferric? [closed]

Like when iron reacts with water there forms iron oxide and hydrogen but how'll we come to know which of three equation will be right equation for reaction? $$\ce{Fe + H2O → FeO + H2}$$ $$\ce{2Fe + ...
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1answer
457 views

What is this white layer on brass?

I have an object made of what I assume to be brass, i.e. an alloy of copper and zinc. The curved parts have both a black layer and a white layer (also note the verdigris (I guess) on the left top, but ...
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1answer
36 views

How can I mask the Chromium (III) and Chromium (VI) ions in my solution?

I want to conduct a quantitative analysis on my acid etching solution for my Aluminum pre-treatment process. The easiest way for me to conduct my quantitative analysis of Al is through complexometric ...
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0answers
149 views

Are Alloy Compositions Given in Weight Percent or Atom Percent

Often times I see alloys described like this, Lockalloy is an alloy that consists of 62% beryllium and 38% aluminum Are the precentages mentioned here in weight percent or atom percent? Is there a ...
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1answer
339 views

Why is RO water more corrosive?

According to several articles from the American Water Works Association, permeate from RO should be stabilized in terms of pH and hardness to avoid corrosion of the distribution piping. How does ...
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0answers
33 views

What fluid can I store metal filings in so they do not oxidize?

I am working on an art project that will involve storing filings of various metals (e.g., iron, copper, zinc) in a colorless fluid. I want to prevent the metals from oxidizing for several years, so ...
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1answer
59 views

Bonding in d10 metals such as Zn

I recently learned about the MO bonding model in metals, where many metal atoms form lots of orbitals close in energy that form bands. However, I can't understand the bonding in d10 metals. It seems ...
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3answers
167 views

Rusting in every other bar

I have noticed that, when a structure with bars (such as a gate or a grate) develops rust, this sometimes happens differently across the bars. In particular, it seems that the bars are alternatively ...
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1answer
460 views

What's the difference between Zinc Ascorbate and Zinc Gluconate?

I've been looking at a dental product for pets, called MAXI/GUARD Oral Cleansing Gel and it states it uses zinc ascorbate/taurine, however in the ingredients I found elsewhere it instead lists zinc ...
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0answers
14 views

Create metallic nanstructure on aluminum or copper film

I want to etch Al/Cu film (0.05 mm thick) to create nanopatterns on to the surface of the film. The etched surface should be metallic. The idea is to develop a simple tribolectric nanogenerator with ...
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0answers
79 views

Why is aluminum oxide resistant to corrosion?

It is common knowledge that aluminum is relatively resistant to corrosion due to its tough oxide layer. The ultrathin (1 nm even) layer is impervious to water and oxygen. What I can't figure out is, ...
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1answer
73 views

Should equiatomic iron–cobalt alloy be written as FeCo or CoFe?

I have an alloy made of 50% iron and 50% cobalt. I see occasionally in the literature this is written as FeCo alloy. But shouldn't it be CoFe alloy since the chemical symbols are supposed to be ...
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1answer
99 views

Does zinc react with nitrogen? [closed]

Does zinc react with nitrogen ? Is this reaction possible: 3Zn + N2 → Zn3N2 Or maybe there are another reaction?
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1answer
49 views

Aluminum powder from aluminum sulfate?

I recently did the experiment where you drop a piece of iron in an aqueous solution of copper sulfate. After a while, the piece of iron gets coated with a fluffy coating of copper that can be dried ...
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1answer
28 views

Is Cu stable as Cu(H2O)2+ for determination on MP-AES? [closed]

I have an unknown sample of mineral which I need to dissolve in nitric acid. I need to analyze $\ce{Cu}$ from it on MP-AES. Do I need to add $\pu{1ml}$ of $\ce{HCl}$ to stabilize $\ce{Cu}$, or it is ...
1
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1answer
38 views

What are coexistent metals?

In ACS Sustainable Chem. Eng. 2018, 6 (10), 12542–12561, I saw the term "coexistent metals", but I could not find a definition for that on the Internet. So what does it mean? Karapinar et ...
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2answers
63 views

rust caused by salt solution & stainless steel

I am not a chemist and I could really use some help for a practical case. I am fermenting vegetables (cabbage, onions, carrots, etc.). I recently switched from glass and ceramic vessels to stainless ...
1
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1answer
92 views

Can a metallic bond with a sea of electrons form inside the human body? [closed]

I’m interested if atoms or ions can for a metallic bond inside the human body? I’m talking about a metallic bond as described here: https://www.britannica.com/science/metallic-bond So I’m thinking of ...

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