Questions tagged [aqueous-solution]

For questions relating to compounds dissolved in water and resulting reactions and acid-base equilibria.

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4
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2answers
53 views

Why do reusable heat packs have a limited time frame before the reaction becomes irreversible?

I have two "rechargeable" heat packs which from my understanding operate on the phase change $$ CH_3COONa_{(aq)} \rightleftharpoons CH_3COONa_{(s)} + \Delta H.$$ Triggering the ...
0
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1answer
38 views

When blue vitriol is dissolved in water [closed]

when CuSO4.5H2O is dissolved in water, what physical and chemical effects happens to its water of crystallization? While solving a stoichiometric problem the ques was that 1litre of CuSO4.5H2O was ...
0
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1answer
84 views

Can Anyone Explain the Mechanism of the Birnbaum-Simonini reaction?

When silver acetate reacts with iodine and $\ce{CCl4}$, it gives esters and 2 moles of $\ce{AgI}$ but when it reacts with iodine and lead acetate, why it gives alkyl halide, $\ce{AgI}$ and $\ce{CO2}$....
0
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1answer
49 views

Calculating the density of a magnesium sulphate solution

I am trying to calculate the density of a magnesium sulphate solution and came across this paper which determines an equation from experiment to do that. However, I am having trouble understanding the ...
0
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0answers
21 views

Aluminum Monoacetate Solubility in Aqueous Medium?

Does anyone have access to the aqueous solubility value of aluminum monoacetate? I would expect it to be slightly soluble but I've searched the internet and haven't found any solubility values. : /
1
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1answer
42 views

Basic behavior of ammonia in aqueous medium [closed]

Thanks to the reversible reaction $$\ce{NH3 + H2O <=> NH4+ + OH-},\tag{R1}$$ we know that ammonia acts as a weak base. However, I was wondering why it ends up forming ammonium $\ce{NH4+}$ and ...
2
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1answer
35 views

What is the mechanism of endothermic dissolution?

My real question is in fact "How can dissolution happen if it's endothermic?" However, there have been many questions regarding this exact topic and the answers about Gibbs free energy ...
0
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1answer
33 views

Water solubility of different types of Iron III

For an experiment I require an aqueous solution of Iron(III). My school has the following compounds, which of them are water soluble? I believe that only Iron(III) oxide is insoluble, but I would like ...
0
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0answers
18 views

Comparative Solubility of Double Salts

Is there a tendency that could be used to generally forecast how a double salt might dissolve in aqueous medium compared to the simple salts of its constituents? Example: There is metal A, metal B and ...
0
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1answer
41 views

Effect of mixing acids on solubility

Please help me clarify the title if you come up with a better way to put it (you certainly will). My question is the following: If you make a mix of equal parts of various acids (Bicarbonate, ...
0
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1answer
46 views

How does solutions of two liquids work? [closed]

I'll start by establishing my potentially flawed understanding of solutions: A solution is a completely homogenous mixture. That means that the two (or more) substances are evenly distributed ...
0
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3answers
67 views

how to separate a mixture of sodium chloride and sodium hydroxide

I recently did an double displacement reaction in that I have formed a solution of water with sodium hydroxide and sodium chloride are dissolved in it. now I want to separate both of them
2
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0answers
29 views

Colligative properties: why does the size of solute not matter?

Colligative properties are defined as the "properties of solutions that depend on the ratio of the number of solute particles to the number of solvent molecules in a solution, and not on the ...
-2
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1answer
38 views

How to make SiO₂ hydrophobic aqueous-solution [closed]

I bought 100g of SiO₂ hydrophobic of 20 nanometers. I'm trying to make my own "car body wax". This "wax" that you can buy on the internet allows to make water repellent on car ...
1
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0answers
46 views

Why is aqueous solution of lauyl glucoside alkaline?

What is the reaction of dissociation of lauryl glucoside? It's aqueous solution pH is much higher than 7, it's definately alkaline. Why is that? It's nonionic surfactant and as far as I know it only ...
0
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2answers
84 views

Fermentation of glucose

I have trouble understanding as to what the last part of the increase in liquid level means. I believe this is the foam formed after the fermentation? I am calculating for the pressure but I have ...
0
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0answers
15 views

Preventing Precipitation/Undilution: Shall I Try Another Solvent?

Thank you for your time in advance. Our facility is about $\pu{4000 ft}$ in terms of elevation. One of the main chemicals we manufacture is RAD140 or $\ce{C20H16ClN5O2}$. We use DMSO ($\ce{(CH3)2SO}$),...
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0answers
18 views

Alkalinity measured by titration after degassing of CO2

I recently received some lab results from a sample which contained a lot of CO2, which degassed before the total alkalinity was measured by titration to a pH 4.5 end point. The best analogue for this ...
-1
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1answer
35 views

Resulting ions concentration after mixing solutions

$\pu{1 g}$ of $\ce{NaHCO3}$ and $\pu{2 g}$ of $\ce{Na2CO3}$ were dissolved in $\pu{50 mL}$ of water known as solution A. Solution A was mixed with $\pu{450 mL}$ of $\pu{0.154 M}$ of $\ce{NaCl (aq)}$ ...
0
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1answer
27 views

Solving detergent powder in a solution

I used a detergent powder mixed with water to clean my espresso machine. Some micro particles of powder are stuck into machine's inner tank. So when I pull the hot water out of the machine's nozzle, ...
-1
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1answer
52 views

How does chromium behave in a carbonate solution? [closed]

I'm wondering how chromium (as a metal or as a salt) behaves in a concentrated carbonate solution. Will it form any, one or several carbonate specie(s)? Will the metal solubilize? How does it affect ...
0
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1answer
35 views

NaHCO3 decomposition dynamics and extent vs Temperature

I'm wondering approximately how fast and to which extent $\ce{NaHCO3}$ will decompose (to $\ce{CO2}$ and $\ce{H2O}$) at $50$, $60$, $70$, $80$, $90$, $100$, $110$, $120$, and $\pu{130 ^\circ C}$. It ...
0
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1answer
59 views

Preparing aqueous solution of ethanol [closed]

You need to prepare $\pu{250.0 mL}$ of an aqueous solution of ethanol in the concentration will be $\pu{0.500 mol L-1}$. You have $\pu{100 mL}$ of a commercial solution of ethanol in water $(35.0\% \,...
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1answer
76 views

Are all gases equal in their ability to carry with them lower volatility matter at a given temperature? [closed]

As we all know water is a great solvent in it's liquid form relative to other substances. I wonder however how it performs as a gas relative to other stuff. Does anyone know how well steam carries ...
-2
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1answer
24 views

Hydrogen and Hydrogen ion

Is it correct that a hydrogen atom only has 1 electron and 1 proton since the atomic mass is 1? Also, is the hydrogen ion composed of a single proton and no electrons? In an ionization process we know ...
-1
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2answers
77 views

Copper anode dissolves in electrolysis of copper sulfate solution [closed]

I did an experiment with copper sulfate where you place two copper rods in an aqueous solution of copper sulfate. You apply an electric current and copper metal builds up on the cathode. I noticed ...
0
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1answer
35 views

Aluminum powder from aluminum sulfate?

I recently did the experiment where you drop a piece of iron in an aqueous solution of copper sulfate. After a while, the piece of iron gets coated with a fluffy coating of copper that can be dried ...
0
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1answer
46 views

Determining the mass of a substance using calibration curve produced by HPLC

I hope everyone is doing well and safe! Yesterday, I was fortunate enough to be taught about how to read a chromatography calibration curve through this stackexchange! Special thanks to those who ...
-1
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2answers
77 views

Determining the formula of sodium carbonate hydrate using acid-base titration [closed]

I found this question online at mathsmadeeasy.com: Sodium carbonate exists in hydrated form, $\ce{Na2CO3 · x H2O},$ in the solid state. $\pu{3.5 g}$ of a sodium carbonate sample was dissolved in ...
0
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2answers
35 views

Composition of arcanite (potassium sulfate) agricultural grade. Potassium content of random drawn sample?

I bought potassium sulfate from this source: Potassium sulfate granulate I'm using it as a potassium additive in hydroponics. The composition is listed as K2O = 50%, S = 18%. This equals about 41.5% K ...
3
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1answer
40 views

Vapors of Aqueous solutions

I'm dealing with a common photoresist developer TMAH (tetramethylammonium hydroxide) and attempting to design a vapor sensor for a sealed chamber. Now I havent been able to confirm what exactly is ...
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0answers
33 views

Arrhenius acids and bases

According to the Arrhenius definition of acids: An Arrhenius acid is any species that increases the concentration of hydrogen ions in its aqueous solution. Hydrogen Chloride gas ionises in water to ...
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1answer
46 views

Behavior of ionic salts in solution

The electrons of an isolated sodium chloride bound pair in vacuum reside at a semi-classical level in their ground state, so that the Born-Oppenheimer approximation applies, and the 'molecule' acts ...
2
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1answer
41 views

Identification of aqueous solutions of sodium hydroxide, sodium acetate and potassium thiocyanate using nickel(II)

I'm very new to chem — taking an intro to chemistry course where we are currently focused on substance identification. I have two substances, both aqueous solutions of either $\ce{NaOH},$ $\ce{KSCN},$ ...
0
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2answers
54 views

Is an aqueous solution of potassium bicarbonate acidic or basic in nature?

The following is the definition of an acid salt according to my textbook: The salts formed by the partial replacement of the replaceable hydrogen atoms (H+ ions) of an acid molecule by a metallic or ...
0
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1answer
92 views

Density of a sodium hydroxide solution

The specific gravity of a $50\%$ aqueous solution $\ce{NaOH}$ is $\pu{1.5298 g cm-3}.$ To my understanding, the $50\%$ means $50$ mass fraction $w,$ i.e. $\pu{500 g}$ $\ce{NaOH}$ in $\pu{500 g}$ $\ce{...
0
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0answers
40 views

Generating hypochlorous acid for disinfecting water using HClO2

I use a product that contains $\pu{700 ppm}$ of $\ce{HClO}$ to disinfect water at $\pu{1 ml}$ per $\pu{1 l}$ and let it rest for about $\pu{2 hrs}$ before I use it so there is no $\ce{HClO}$ left ...
0
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0answers
31 views

Zinc salt with a very high relative aqueous solubility?

Zinc bromide, iodide, and chloride are highly soluble in water, both in absolute terms, and relative to other metals. I think however that there is a zinc compound with even higher relative aqueous ...
0
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1answer
70 views

Find volume of ammonia gas required to prepare a solution of given pH [closed]

Calculate the volume of gaseous ammonia $(K_\mathrm{b} = \pu{1.8E-5})$ to dissolve (at NTP) in $\pu{100 mL}$ of water in order to obtain a solution with $\mathrm{pH} = 11.0.$ Consider volume variation ...
2
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2answers
64 views

Does magnesium sulfate in aqueous solution form magnesium (hydrogen-)carbonate when hydrogen carbonat is present?

I'm using an additive of magnesium sulfate to complement my fertilizer. The additive lists the following ingredients: I know that it does NOT contain magnesium oxide, because due to historical / ...
4
votes
1answer
139 views

Common Ion Effect - Ionic Equilibrium

Question In which of the aqueous solutions of the following, dissociation of $\ce{NH4OH}$ will be minimum? A) $\ce{NaOH}$ B) $\ce{H2O}$ C) $\ce{NH4Cl}$ D) $\ce{NaCl}$ My Thoughts My book says that ...
0
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1answer
57 views

Additive for water to increase the viscosity to a value between 5 and 20 cP [closed]

Is there an additive that I can add to water that will increase the viscosity to a value between $5$ and $\pu{20 cP}$? Ideally, I would like the mixture to be newtonian and since I will be working ...
0
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1answer
31 views

Creating 100mg/L aspirin solution

I plan on creating 100 mL of 100mg/L aspirin solution by dissolving 10 mg of pure aspirin powder in 100 mL of buffer solution (of different pHs). Problematically, aspirin doesn’t tend towards ...
13
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5answers
3k views

Is it possible to achieve a level of “truly zero” concentration? [duplicate]

If we take some aqueous solution and dilute it further and further, will the concentration of the solution ever get to zero? I would say no, simply because total dilution implies that all the ...
1
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1answer
96 views

Molar conductivity of coordination compound [duplicate]

The compound is $\ce{[Cr(H2O)6]Cl3}$. Which isomer has least molar conductivity ? Correct answer : $\ce{[Cr(H2O)4Cl2]Cl.2H2O}$ My answer : $\ce{[Cr(H2O)3Cl3].3H2O}$ Molar conductivity is directly ...
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0answers
23 views

What is the pka of dibromoacetic acid?

There is a reference of 1.48 value at room temperature which is a different value from an experimental study.
1
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1answer
43 views

Conductivity of molten or aqueous salts [closed]

If there is a 1M aqueous solution of 1 liter NaCl (aq), and the molar conductivities of the solution and the chloride ions were found to be $x$ and $y$ respectively, is it accurate to say that the ...
3
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0answers
356 views

Number of moles of acidified potassium dichromate required to liberate 6 moles of iodine from an aqueous solution of iodate ions

I came across this question in a recent exam I had taken: How many moles of acidified $\ce{K2Cr2O7}$ is required to liberate 6 moles of $\ce{I2}$ from an aqueous solution of $\ce{I-}$ ? So this is ...
0
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0answers
57 views

Effect of adding an acid or base to water with respect to concentration of ions

So I know that there's auto-ionization of water according to: $$\ce{2H2O <=> H3O+ +OH-} \tag{1}$$ If I have pure water where the concentrations of both $\ce{H3O+}$ and $\ce{OH-}$ is $10^{-7}$ ...
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1answer
58 views

What is the enthalpy change of solution of oxygen and water? [closed]

What is the enthalpy change of solution of oxygen dissolved into water?

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