Questions tagged [reactivity]
Applied to a chemical species, the term expresses a kinetic property in reference to another species. The tag should be applied to questions seeking answers with respect to the reactivity (or unreactivity) of a certain chemical compound, species, molecular entity and/or functional groups. It must not be applied to questions about the stability of certain chemical species.
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Reactivity of Alkyl Halides with E2 with same number of substituents in the end
I have a question regarding the reactivity of alkyl halide for E2. I know that the general rule is tertiary alkyl halide reacts the fastest with E2, and primary alkyl halide reacts the slowest.
I was ...
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Order of radical dimerization ability
In a question I came across recently, it was asked to arrange the following radicals in the ascending order of dimerization ability.
I have read about the triphenylmethyl radical undergoing Gomberg ...
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Effect of phosphoric acid on chrome plating
Wondering whether phosphoric acid a suitable agent to clean chrome plated bathroom figments - a metal base shower head
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Improve the leaving capability of a leaving group (F-) with electron density donating groups (EDP) in close proximity (neighboring group effect)?
I have a situation in which I want to hydrolyze a phosphonic acid halide under basic conditions. In my specific case, the halide is a fluorine substituent. Other halides like chlorine and bromine are ...
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Drano and Bleach reaction? [closed]
I’m not sure if anyone can answer this but I might’ve messed up, or I’m just overreacting.
My bathtub has been clogged for about a month now and I used a splash of Drano to see if it would do anything,...
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Why do stable covalent compounds react with water [closed]
I am curious why a discrete covalent molecular substance, say CO2, would react with water to form an acid, what happens in such a reaction? I'm assuming it has something to do with disassociated ions ...
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Is there an international standard for rating the danger of chemical elements?
I'm writing a small little tool (something like an interactive periodic table) and I wanted a good "guesstimate" of the danger of certain elements, to visualize across said table.
I could go ...
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Why does silver react preferentially with chlorine instead of chromate?
Mohr's method of precipitation titration relies on the fact that silver reacts preferentially with chloride ions instead of chromate ions in solution. When I searched up why this is true, the only ...
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Why can't RX add to alkenes / alkynes like HX?
With an analogous mechanism: C bonded to X has a δ+ charge and attacks the pi electrons to form a carbocation intermediate, with X- as a leaving group. X- then adds to the carbocation to neutralize it....
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Why are cyanamides more electrophilic than nitriles?
According to https://www.researchgate.net/publication/6642597_A_generally_applicable_method_for_assessing_the_electrophilicity_and_reactivity_of_diverse_nitrile-containing_compounds, cyanamides (...
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Can you oxidize gold using only oxygen?
I keep reading that gold does not react with oxygen, but I also see information about gold Oxides (ie: aurous oxide, Au2O and auric oxide, Au2O3)
Knowing that there is a way of getting gold oxide ...
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Can the relative velocity of two colliding molecules be too large to allow reaction to occur?
In a collision between two molecules, can the relative velocity of one with respect to the other be too large for a reaction to occur? For example, suppose that two molecules collide with (a) a ...
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Why bromoacetone is more reactive towards SN2 than alkyl bromides? [duplicate]
Compare the rates towards SN2 reaction:
I got the point that 2-bromobutane d is a secondary halide, so the steric hinderance is highest making it least reactive among the four. Both b and c are ...
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Can alkyl halides react with guanidine/guanidino groups?
I wonder how the π delocalization of guanidino groups affects the reactivity of the terminal nitrogens with respect to alkyl halides compared to, say, primary amines?
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What drives double displacement reactions?
I have two questions:
I understand that in a displacement reaction the more reactive element displace the less reactive element. But why? In the reaction with Zinc and Copper Sulfate, we form Copper ...
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Understanding grades of steel for cookware. 18/10 vs 18/8
I am looking for a stainless steel cookware and while researching on the best kind of stainless steel cookware, I came across this comment on youtube:
Actually 18/10 steel is better and costlier. You'...
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What makes a compound high or low energy and why does that relate to reactivity? [closed]
After reading about thermodynamic stability, it now makes sense to me how the enthalpy of a reaction relates to the thermodynamic stability of a compound.
However, when looking for a clear way to ...
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Does manganese reacts with water at "not" standard conditions?
In my answer, I stated that manganese is said to not react with water under normal conditions although some sources say it reacts with water to liberate hydrogen gas. Does it implies that it reacts ...
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Does solid manganese reacts with atmospheric air when heated?
As discussed in my answer, manganese is not particularly reactive to air. The surface of manganese lumps oxidize to a minor extent but when it is finely divided, it becomes pyrophoric and burns in air....
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Oxidation Reactions/Reactivity of Manganese Metal in Air and Water
I am planning on doing some reactions that lead to Manganese metal and a neutral solution containing $\ce{Mn^{2+}}$ as by-products, and I wanted to try some things out with the Manganese as well.
...
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Where does the energy required to initially begin the reaction of iron and oxygen come from?
When iron is left outside, over time it reacts with oxygen to form iron oxide or rust. But how does the oxygen react with iron, isn't iron held together by strong metallic bonds? Where does this ...
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How to explain mesylate structural homologues (e.g., "esylate") being weaker leaving groups than mesylate itself?
I came across a piece of scientific literature (https://patents.google.com/patent/US20080045602A1/en) that would seem to imply leaving groups formed by reacting hydroxy groups with, e.g., ...
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How should the reactivity of 1-propanesulfonyl chloride be expected to compare to tosyl chloride for sulfonylation?
I've come across some scientific literature (e.g., https://doi.org/10.1021/jm400751p) that notably feature 1-propanesulfonyl chloride (PsCl) in the selective activation of hydroxy groups, such as a ...
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Does nickel precipetate gold and copper?
I dissolved some CPU s and RAM s in aqua regia the day after I found a green solution with black powder in the bottom. So what just happened is it nickel or tin from solder?
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Displacement Reaction [closed]
In a displacement reaction I understand that the more reactive metal essentially takes the place of the less reactive metal. But I can't seem to understand how this more reactive metal can break the ...
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Reactivity vs Stability: Chlorine Trifluoride
Chlorine trifluoride shows up on many pop science content, which is how I learned about it just today, as an incredibly reactive compound capable of oxidizing seemingly incombustible substances (glass,...
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Why urea crystallizes in aqua regia? [closed]
Recently I stripped gold from old cpu's with ferrous chloride after that I rinsed the cpu's and dissolved them in the aqua regia to get the gold inside when all done, I added urea solution to the ...
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In school, I learnt that Potassium is the most reactive element in the reactivity series. I thought it was Francium?
In school, I learnt that Potassium is the most reactive element in the reactivity series. In the periodic table, the further you go down the more reactive the elemnt is. If this is true, then shouldn'...
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Why does a carbon double bond "break readily" but this is not so for other elements (nitrogen double and triple bonds are stronger)? [duplicate]
A level chemistry student here, fairly basic question. We always learnt (from GCSE bond enthalpies) that "Bigger bonds are stronger", so to speak; my teacher often quoted $\ce{N#N}$ as very ...
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Can metal displacement reactions happen with insoluable salts?
I know how normal metal displacement reactions work. If one metal is more reactive than the other, they will displace.
For example, normally for this reaction:
$$\ce{Fe_{(s)} + 2AgCl_{(aq)} -> Fe^{+...
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Why doesn't XeF6 displace oxygen from water?
Consider the following reactions (unbalanced):
$$
\begin{align}
\ce{XeF2 + H2O &→ Xe + HF + O2} \tag{a} \\
\ce{XeF4 + H2O &→ XeO3 + Xe + O2 + HF} \tag{b} \\
\ce{XeF6 + H2O &→ XeO3 + HF} \...
user121185
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Are intermediate bulk container units suitable for storage of isopropyl alcohol? [closed]
I'm working in water treatment construction and my boss is going to be stocking isopropyl alcohol (IPA).
He wants to store the chemical in bulk, with amounts ranging from 5000 L to 10000 L in IBC ...
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How is propene more reactive as well as more stable than ethene?
I know that hyperconjugation stabilises a double bond. But in propene an electron-donating group $(\ce{-CH3})$ is increasing the electron density at the double bond, so its nucleophilicity should be ...
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Why does the reaction of Brady's reagent and cyclohexanone not also form an enamine-type product?
In this reaction in a Khan academy video, cyclohexanone reacts with Brady's reagent to form hydrazone product.
My question is why doea Brady's reagent + cyclohexanone not also form an enamine product ...
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Way of determining based on atomic characteristics what to expect during reaction [closed]
So I believe the question was clear, but here goes.
I would like to know the rules for determining the following properties of a molecule, and/or of a reaction it produces with another molecule or ...
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How displacement reaction actually taking place? [closed]
"When a zinc plate placed in copper sulphate solutionfor some time,after sometime we can see holes in plate , why?"
So this was a question in my book , I don't want answer of this one.
But I ...
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What are some other examples of non-nucleophilic acids, other than boronic acids?
Boronic acids can react as a Lewis acid, after reaction they are not good nucleophiles as the conjugate base. What are some other examples of such non-nucleophilic acids (or acids that have a non-...
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Reactivity of Benzaldehyde vs Acetaldehyde and Benzoic acid vs Acetic acid
I was trying to compare the reactivity between acetaldehyde and benzaldehyde. After some googling, I found out that benzaldehyde is less reactive than acetaldehyde because the benzene ring can ...
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Can stainless steel be electrically insulated with (oven-dried) Sodium Silicate Solution?
Can I electrically insulate stainless steel by painting Sodium Silicate solution on it and heating it to 200C for 30min or so?
The solution should be conductive, and I've been told (to be verified) ...
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Effect of R/S configuration on reactions not involving the stereocentre
An exam question involved the following reaction -
+ forms
Both reactants (2-methylbutanoic acid and 2-methylbutanamine) are optically active. The question used pure R-enantiomer of the acid, and a ...
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Why does radium form a nitride rather than oxide when exposed to air?
The Wikipedia article states:
Pure radium is silvery-white, but it readily reacts with nitrogen (rather than oxygen) on exposure to air, forming a black surface layer of radium nitride ($\ce{Ra3N2}$)....
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Bond Polarity vs bond length's effect on reactivity of haloalkanes
My textbook says:
Carbon acquires partial positive charge whereas halogen acquires partial negative charge. Halogen becomes nucleophilic in character, which can be replaced by another nucleophile on ...
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Relation between Ionization energy and reactivity
So I was learning about the periodic table where I came across the topic of ionization energy. As a general trend the Ionization energy decreases as we move down a group with a few exceptions such as ...
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The dependency on electron density in the reactivity order of electrophilic and nucleophilic additions
It is well-known that for electrophilic addition across an alkene, the reactivity increases when intermediate carbocation is more stable (eg. addition of $\ce{HBr}$ or acid-catalyzed addition of $\ce{...
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Why is it technically inaccurate to say that the decrease in reactivity of halogens is due to decreasing electronegativity?
I came across the following information in this post.
Below the infographic there is a paragraph with a disclaimer:
As another disclaimer, the reactivity of the halogens decreasing down the group ...
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Reactivity order of DIBAL-H and diborane with esters and acids
I have been taught in class that
DIBAL-H is more reactive towards esters than carboxylic acids while opposite is true for diborane.
Also DIBAL-H mentioned is taken under low temperatures (−78 °C).
I ...
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Competition between aromatic sulphonation and nitration
Say you take a substituted benzene* and react it with oleum and nitric acid. Would it result in a nitrated ring, a sulphonated ring, or some sort of a combination?
Thinking about it in terms of the ...
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Will dioxygen difluoride set fire to sand? [duplicate]
I've heard that dioxygen difluoride (a.k.a FOOF) would set fire or react with nearly everything including sand ,bricks or even ice. Is this true?
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Regarding stability and reactivity of m-xylene
I came across the following two details about m-xylene:
m-Xylene is thermodynamically most stable compound among o-xylene, m-xylene, and p-xylene.
m-Xylene is most reactive towards nitration and ...
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Orbital Interaction for electrophile and nucleophile
Clearly, the above diagrams depict the interaction between empty orbital of electrophile with filled orbital of nucleophile. We may assume that the HOMO of nucleophile being more electronegative will ...
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