Questions tagged [solutions]

This tag should be applied to questions dealing with solutions of any kind. A solution is a liquid or solid phase containing more than one substance where, for convenience, one (or more) substance(s) called the solvent is treated differently from the other substances, which are called solutes. If water is the solvent, then the more appropriate 'aqueous-solution' tag should (also) be specified.

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13 views

What is it meant by “preparing solutions on a blister”?

I was recently looking into an aspirin hydrolysis preparation lab and noticed the following: (This preparation was taken from http://www.kii3.ntf.uni-lj.si/analchemvoc2/file.php/1/HTML/SPEKTRA/...
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1answer
24 views

opening valve separating two volatile solutions [closed]

Let there be two containers A and B containing two volatile solutions (ideal) of pure liquids P and Q respectively. The containers are connected by a tube such that only vapours can travel through ...
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2answers
13 views

Why is water transferred from a beaker of pure water to a beaker of sugar solution when placed in the a closed container?

I know that there is something to do with the vapour pressure of pure water being higher than the vapour pressure of the sugar solution, but I still can’t really explain what happens on a molecular ...
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1answer
70 views

In what solvents does ionic association occur?

When a ionic compound like $\ce{NaCl}$ dissolves, it doesn't always full dissociate due to ionic pairing. This is measured by the van 't Hoff factor. Now, this is what I'm looking at for my chem ...
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1answer
21 views

Hydrogen and Hydrogen ion

Is it correct that a hydrogen atom only has 1 electron and 1 proton since the atomic mass is 1? Also, is the hydrogen ion composed of a single proton and no electrons? In an ionization process we know ...
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3answers
44 views

Why does Vapor Pressure decrease on addition of solute? [duplicate]

Consider a vessel with a volatile liquid in it. Let's say it has a vapor pressure $P^0$ when it is pure. Now a non-volatile solute is added to it. Its vapor pressure decreases as $P^0\chi_{solvent}$. ...
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1answer
25 views

When is Raoult's Law valid for solid-liquid solution?

Raoult's Law for solid-liquid solution is stated as such in my books that it is applicable for all non-volatile solutes. However different solutes must have different attractive or repulsive forces ...
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2answers
66 views

Copper anode dissolves in electrolysis of copper sulfate solution [closed]

I did an experiment with copper sulfate where you place two copper rods in an aqueous solution of copper sulfate. You apply an electric current and copper metal builds up on the cathode. I noticed ...
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3answers
1k views

What does washing and drying a solution mean?

After combining two solutions, a direction in a 1970s British chemistry book says to wash the new solution with a mixture of baking soda, table salt, and water. Then it says to dry it with anhydrous ...
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2answers
111 views

How does a shock, such as the snap of the disk in a reusable hand warmer, trigger the re-crystalization of a supersaturated solution?

Reusable handwarmers are made of something dissolved nearly to its saturation point in hot water (Sodium Acetate in the case of HotSnapz) at a high temperature, and then cooled to a temperature at ...
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1answer
37 views

What is the temperature needed for a reflux using a mix of solvents as the reaction medium? [closed]

I had a quick query regarding the setup of a reaction. The procedure that I am working from states that I need to put my reaction mixture under reflux for 3 hours. The solvents used are diethyl ether (...
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1answer
309 views

Detailed kinetic explanation for vapor pressure reduction by dissolved solute?

The following problem was asked in JEE Mains 2020 (Sept 2, Shift 1), An open beaker of water in equilibrium with water vapor is in a sealed container. When a few grams of glucose are added to the ...
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1answer
81 views

Who came up with C1V1 = C2V2? [closed]

I was wondering if there is an original scientific publication showing why $C_1V_1 = C_2V_2$ works. Or perhaps, who described/used it first?
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21 views

Unscented volatile oil to mix with pine tree sap [closed]

I would like to use pine tree sap to apply to the skin. However, the sap is too viscous to be used conveniently so I would like to thin it out. All of the pine salve recipes use various oils which ...
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0answers
19 views

Solubility Product, and it's relation to solubility

In order to remove temporary hardness of water, it is boiled. On boiling, while Ca(HCO3)2 gives CaCo3(ppt.) , Mg(HCO3)2 gives Mg(OH)2(ppt.). According to my book precipitation of Mg(OH)2 occurs due to ...
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25 views

Is sulfuric acid necessary for Kevlar synthesis?

In the production of Kevlar, the 2 monomers needed for its creation are reacted in a solution. Due to it being water-insoluble, sulfuric acid is used. My question: Can other chemicals be used as well (...
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1answer
33 views

Actual color of colloids [closed]

I have read that the color of colloid depends upon the wavelength of light scattered by the dispersed phase and also in the sense in which the receiver receives the light. If all of this depends on ...
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0answers
50 views

Freezing point of solution of Water, Ethanol and Sugar (aka, Limoncello)

I'm looking for a diagram of the freezing point of a water solution depending on its content in sugar and ethanol. More colloquially, I want to know how to balance alcohol and sugar so that my ...
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1answer
69 views

Find volume of ammonia gas required to prepare a solution of given pH [closed]

Calculate the volume of gaseous ammonia $(K_\mathrm{b} = \pu{1.8E-5})$ to dissolve (at NTP) in $\pu{100 mL}$ of water in order to obtain a solution with $\mathrm{pH} = 11.0.$ Consider volume variation ...
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1answer
40 views

Ionisation vs Dissociation

This is a statement given in my book: A strong electrolyte is completely ionised at all dilutions but not completely dissociated. But the book also uses the terms "Ionisation" and "...
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2answers
589 views

Can aluminium form blue-colored solution in liquid ammonia?

I am a high school student and in one class, my inorganic chemistry teacher told group 1 elements with the exception of lithium and group 2 elements with exception of Be form blue-colored solutions ...
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0answers
28 views

What is vacuum-assisted ultrasonication?

This quote from a methods section of a paper: [samples were] ultrasonicated for approximately 30 min to ensure adequate dispersion of the components throughout the mixture. The solution was then ...
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0answers
18 views

How does the solubility of hydrated ions differ from unhydrated ions?

So the hydrated compound I am thinking about specifically is pentahydrate copper sulphate. I know when you put ionic compounds in water, the ions because hydrated by the water molecules. However, what ...
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1answer
51 views

Extrema in free energy of a solution?

I am a high school student reading about the second law of thermodynamics, and one of the equations given was the free energy change in dilution. $$\Delta G_{\text{dil}} = -RT \log(C_1/C_2)$$ This ...
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1answer
78 views

Why sugar solution/sugarcane juice becomes sour when kept for certain time?

I stir-dissolve some sugar in a cup of water and then keep it open for certain time (say a few hours), when I taste it I feel that it has became sour. I have observed the same thing many times when I ...
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1answer
44 views

Molality of solution to be used when finding water separated from solution as ice

Question $\pu{1 kg}$ of a solution of cane sugar is cooled and maintained at $\pu{-4 ^\circ C}$. How much ice will separate out if molality of solution is $0.75$? $K_\mathrm{f} \ \text{(water)} = 1....
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1answer
86 views

How is the formula of mean activity coefficient derived?

The mean activity coefficient is defiend as follows: $$\gamma_\pm = (\gamma_+\gamma_-)^{1/2}.\tag{1}$$ If Debye-Hückel equation $$-\log\gamma_i = 0.5z_i^2\mu^{1/2}\tag{2}$$ is used, then the mean ...
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0answers
36 views

Solubility of salts in water

I came across the formula for enthalpy of solution, which is equal to the sum of lattice enthalpy and hydration enthalpy. Therefore, for salts that have endothermic dissolution, the lattice enthalpy ...
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1answer
44 views

Are colligative properties applicable for volatile liquids and gases in liquid solvent? Why/Why not?

My teacher told me that the expressions for calculation of colligative properties like lowering in freezing point are only applicable if the solute is non volatile liquid or a solid. We cannot apply ...
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1answer
64 views

Caustic and Toxicological Determination [closed]

I need to determine whether or not a product that I am importing is "toxic" and or "corrosive" as defined below. But I am a chemistry n00b — that is to say I have virtually zero ...
2
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1answer
72 views

At what composition is Maximum deviation from Raoult's law observed?

Raoult's law states that in an ideal binary solution of two volatile components, the partial vapour pressure of each component is proportional to its mole fraction in the solution. A plot of total ...
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2answers
718 views

Limitations of Henry's law

Consider the diagram Henry's law is a gas law that states that the amount of dissolved gas in a liquid is proportional to its partial pressure above the liquid. The proportionality factor is called ...
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1answer
42 views

Do pipettes always outclass glass syringes?

I was previously working in a lab preparing lots of samples for gas chromatography that exclusively used glass pipettes and was able to get really high precision between replicates. Now I'm working on ...
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1answer
20 views

Vapour Pressure of solutions and mol fractions

From a solution (ideal) which contains the components A and B ,the vapours over the solution at a temperature T are collected and condensed into liquid and again brought to the same temperature T. ...
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1answer
32 views

How does sodium rosinate enhances lathering property? [closed]

Why don't we use sodium carbonate or sodium stearate? What does sodium rosinate contain that the other two don't?
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0answers
27 views

Column Dispersive Mass Balance analytical / numerical solution

Is there any analytical solution for the most common expression of column mass balance: $\dfrac{\partial C}{\partial t} + \left(\dfrac{1+\varepsilon}{\varepsilon}\right)\dfrac{\partial q} {\partial t} ...
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0answers
59 views

Understanding formulas for PZT

In the slides i'm studying (about the production of PZT), is given the following formula for lead zirconate titanate : $$\ce{PbZr(Ti)O_3}$$ with the explanation: It is a solid solution of two oxides: ...
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1answer
45 views

Doubt regarding Raoult’s Law definition

Raoult’s law states that: The partial pressure of any volatile constituent of a solution at a constant temperature is equal to the vapour pressure of pure constituent multiplied by the mole ...
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2answers
92 views

Definition of “solution” [closed]

In my textbook “solutions” are defined as follows: Homogenous mixtures of two or more substances are known as solutions. Should the two substances always be non-reacting? The definition has no ...
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2answers
101 views

How can one reclaim isotopic cadmium from a solution of acid, i.e. H2SO4 or HCl etc.?

I have dissolved isotopic cadmium-114 with $\ce{H2SO4}$ and or $\ce{HCl}$. Now that I have the cadmium-114 in solution, precipitating out $\ce{CdSO4}$ and or $\ce{CdCl2}$, how can I reduce these ...
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4answers
93 views

How many grams of sodium phosphate must be added to precipitate as much of one ion as possible?

Problem text: Solid sodium phosphate is slowly added to $\pu{200 mL}$ of a solution containing $\pu{0.002 mol}$ of aluminum chloride and $\pu{0.001 mol}$ of calcium chloride (assuming no volume ...
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1answer
55 views

Using solubility product to determine the mass of the precipitate of a reaction

I mix together $\pu{100 mL}$ of an aqueous $\ce{NaCl}$ solution at $\pu{0.5 M}$ and $\pu{100 mL}$ of an aqueous $\ce{AgNO3}$ solution at $\pu{0.3 M}$. Assuming that the solubility of $\ce{NaCl}$ in ...
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1answer
51 views

Creating a chemical solution with water and chlorine

I bought a swimming pool for my kids and also a measurement instrument for measuring the amount of chlorid in the pool in mg/l. The problem is now that you have to calibrate the instrument before ...
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1answer
83 views

Radioactive decay of ions in solution [closed]

What happens when ionic salts in solution decays? For example, if I had a handful of Francium-223 Palmitate(Francium salt of palmitic acid) and I were to put it in solution, how would the francium ...
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1answer
53 views

Calculating concentration of OH⁻ ions [closed]

Calculate concentration of $\ce{OH-}$ ions in $\pu{0.66 mol L^-1}$ solution of $\ce{NH4+}.$ I think that there might be something missing, as the only law I have for this kind of problems is $$[\ce{...
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1answer
35 views

Deviations from Raoult's Law [closed]

A solution of two compounds may be an ideal solution and follow Raoult's Law, or it may show a positive or negative deviation from Raoult's Law. How to predict that whether a solution of two given ...
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3answers
2k views

Can a solvent be a solid?

Can a solvent be a solid? I do not think so. But is it possible for a solvent to be a solid?
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1answer
40 views

Determining solvent and solute [closed]

On which conditions does determining solvent depend on? 1. the higher boiling indicates the solvent the material with the higher concentration is the solvent the solvent is kept first in a pot. ...
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1answer
54 views

Creating a 10 ppb Lead Nitrate Solution

I’m trying to make a 10 ppb Lead Nitrate solution as part of a concentration calibration step for a Beer Lambert’s Law experiment. I plan on performing a dilution in three steps. The calculations have ...
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1answer
37 views

thinking about osmotic pressure when liquid is replaced by gas

An option in my test says: "The osmotic pressure of a dilute solution is the same as it would exert if it exists as a gas in the same volume of the solution and at same temperature." I'm not able ...

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