Questions tagged [density]
For questions involving (theoretical or experimental) comparison of density of elements or substances, calculating density of solutions, effects of temperature on density, and other chemical aspects of density.
169
questions
0
votes
1
answer
57
views
Molar Concentration as a Function of Mole Fraction
I am using the ideal gas law for a gas mixture and would like to confirm the following derivation and simplification.
Starting from the ideal gas law:
$$\rho = \frac{P \cdot M}{R \cdot T}$$
where:
$\...
0
votes
3
answers
54
views
Search for liquid (Density atleast 1.01g/cm^3) [duplicate]
For an experiment, I need an liquid which is only slightly denser than water but is not a liquid mixed with water.
Essentially I need to layer 3 liquids, one of which is water (density: 1.0g/cm^3), ...
5
votes
2
answers
573
views
Searching for liquids with a high boron density
TLDR:
I need a liquid with a high mass density of boron that has several physical properties constraints:
Needs to be similar in density and viscosity to water (replacing water in the system).
Needs ...
0
votes
0
answers
18
views
Why is water the densest at 277K? [duplicate]
From what I have seen/heard of, all the elements get denser and denser the cooler its temperature is; but for water, it isn't like that. After 277K, the water expands. Why is this? Is it because the ...
0
votes
0
answers
63
views
Why is ammonia more energy dense than ammonium nitrate?
On wikipedia's extended reference table they state that ammonium nitrate has an energy density of 1.4Mj/kg or 2.5MJ/l. Ammonia was said to have an energy density of 16.9MJ/kg or 11.5MJ/l. This seems ...
-2
votes
1
answer
93
views
What is the cause of different metal densities? [duplicate]
What causes differing density?
Is one metal more dense than another because the atoms are larger (more mass per atom), or because the atoms are closer together? Or both?
Example:
Aluminum
Density: ...
-3
votes
2
answers
73
views
Volume of gas mixture [closed]
I have inlet to a reactor formed by equimolar CH4 and NH3, I want to find the volume of this gas mixture.
First I wanted to calculate the sum of individual volumetric flow rates from V = m*rho. ...
-1
votes
1
answer
101
views
meaning of ingredient labelling `w/v`
A mouthwash states it has among other ingredients, menthol 0.042% w/v. What is the correct interpretation?
This chemistry.stackexchange.com answer says it's weight per volume with unspecified units, ...
-2
votes
1
answer
120
views
Density of unknown metal
An empty flask weighs $\pu{115.713 g}$. When filled water at $\pu{20 °C}$ it now weighs $\pu{365.263 g}$. The flask is then emptied and a $\pu{15.000 g}$ sample of unknown metal is added to it. It is ...
0
votes
1
answer
164
views
At what temperature is bismuth the densest?
Both water and bismuth have denser liquids compared to solid forms, and we know water is the densest at the temperature of about 4°C.
Does the same thing apply to bismuth? Of course, I know the ...
0
votes
1
answer
55
views
Any way to predict what quantities of heptane and chloroform will match the density of water?
I am trying to make a solution of heptane and chloroform that matches the density of water.
Is this something which must be done experimentally as it is generally unpredictable? Does a software exist ...
-2
votes
1
answer
80
views
Find the w/w percentage nitrogen in an ammonium nitrate solution
MCQ Question:
What is the w/w percentage of nitrogen (N) in an ammonium nitrate solution with a density of 1.05 g/cm3 and a molar concentration of 2.1 mol dm-3?
(a) 2.8 %
(b) 11.2 %
(c) 16.0 %
(d) 5.6 ...
2
votes
1
answer
2k
views
What is the unit of molar density?
I'm reading Unit operations of Chemical Engineering, 5th edition by Warren McCabe.
The authors defined the molar density as $\rho_{M} = \frac{n}{V}$. Here, $n$ and $V$ represent the number of moles ...
0
votes
1
answer
79
views
Identify two hydrocarbons using volume and density [closed]
Question:
A gaseous mixture with volume 16.8 dm3 contains two unsaturated neighboring hydrocarbons belonging to the same group. Density of the mixture was 14.4 times as hydrogen gas.
What could be ...
0
votes
2
answers
105
views
Density of dissolved and non-dissolved salts
I am doing a calculation, which needs to be 100% correct. My question is as follows; Does the density of dissolved salt differentiate from the density of non-dissolved salts?
My specific problem is a ...
0
votes
0
answers
151
views
Find volume of methanol produced via reaction between carbon monoxide and hydrogen gases
Methanol is manufactured by the reaction of carbon monoxide gas with hydrogen gas. If a $95~\%$ yield is usually obtained, approximately how many liters of hydrogen gas at $\pu{350 °C}$ and $\pu{300 ...
3
votes
2
answers
371
views
My experiemental density of H2 does not match the published data. What causes this discrpenecy?
I placed 1 gram of NaBH4 in a balloon and placed it over a glass round bottle filled with water and acetic acid. While secured, I emptied the balloon into the bottle and made sure to wash the inside ...
-3
votes
1
answer
65
views
Is there any material that, subjected to electricity, extends in size in multiples without substantial change in heat for human use? [closed]
Is there any material that can molecularly restructure so as to expand its intra- or inter-molecular distance by no less than three-fold without substantially losing its structural integrity and ...
1
vote
1
answer
326
views
Why the density of liquid decreases and density of vapour increases as we approach towards the critical state/point
Pressure and temperature have opposite effects on density. As temperature increases at constant pressure density decreases and as pressure increases at constant temperature the density increases (and ...
1
vote
0
answers
49
views
What is the sample density used for a buoyancy mass correction?
For a lab exercise to calibrate volumetric glassware I was given the follow equation to correct weighings for the density of air:
$$m_\mathrm{c} = m_\mathrm{s}\,\frac{1 - \rho_\mathrm{a}/\rho_\mathrm{...
-3
votes
1
answer
292
views
Additives to increase water density and solubility [closed]
What additives do I need to add to a water-based drink (coffee or tea for example), to increase its density and to make the drink insoluble (like olive oil for example) in salt sea water or inland ...
1
vote
0
answers
76
views
IAPWS-IF97 empirical equations for water and steam
IAPWS-IF97 provides empirical equation the dynamic viscosity and the thermal conductivity for water, are there any formulas by IAPWS-IF97 for the density and the specific heat capacity of water?
I ...
0
votes
3
answers
782
views
How do water vapor molecules push other air molecules away?
I've read that when water vapor enters the atmosphere, the vapor molecules push the oxygen and nitrogen molecules out of the way and occupy their space.
But if water vapor molecules are lighter than ...
0
votes
1
answer
450
views
How molarity and mass fraction are related? [closed]
Concentrated sulfuric acid contains very little water, only $5\,\%$ by mass. It has a density of $\pu{1.84 g mL-1}$. What is the molarity of this acid?
I know to use the molarity $c$ is in $\pu{mol L^...
-1
votes
1
answer
331
views
Why is Molar Mass of a gas twice the vapour density?
I've seen this relation at a number of places, and I can't get why. A simple Google search doesn't give me a simple answer either.
Also, are there any exceptions/conditions for this relation to be ...
1
vote
0
answers
63
views
COSMO Segment charge density via NWChem [closed]
I'm struggling to get COSMO segment surface charge densities that I need to create the sigma profiles in COSMO-SAC.
I am not a chemist by training, so please explain like I am five. I've read papers ...
-3
votes
1
answer
959
views
Why are certain gases with higher molar masses less dense than the ones that have a lower one?
Neon, despite having a larger molar mass than nitrogen, oxygen and fluorine, is less dense than all of them. This also goes that fluorine (again) and chlorine are both denser than argon, even though ...
-7
votes
1
answer
210
views
Can someone explain this answer in detail? [closed]
The density of iron is $\pu{7.874 g/cm3}$ and its unit cell volume is $\pu{2.364E-23 cm3}$. These values indicate that there are: two Fe atoms per unit cell and the metal is body-centered cubic.
I am ...
1
vote
0
answers
27
views
Saturated vapor and liquid densities (VLC curve) from Helmholtz free energy equation of state
I have been reading about the statistical associating fluid theory (SAFT) which computes the Helmholtz free energy ($A$) from the SAFT EoS (a hell lot of equations) for a molecule of interest, and is ...
0
votes
1
answer
7k
views
Is the density of a mixture ever just the sum of the densities of each species in the mixture? [closed]
My current hypothesis is that this is true when the volume is finite and perhaps this would cause the densities to be additive.
For example, imagine there is a closed container, 2 L in size. And ...
4
votes
4
answers
394
views
A dense solute for oils that's easy to acquire
I'm working on a crafts project that is basically putting oil, water and glue in a bottle together with glitter just so you look at it. I want to see how it looks if the density of the oil is very ...
0
votes
0
answers
161
views
Current density from overpotential
A current of $190$ mA is measure for a $2.5$ cm$^2$ electrode in contact with a solution containing M$^{2+}$/M$^{3+}$ metal ions at room temperature at a overpotential of +$180$mV. The transfer ...
1
vote
0
answers
82
views
Water density in the calculation of the ionic product of water
In 2019 the International Association for the Properties of Water and Steam released this document for the semi-empirical calculation of the ionization constant of water: http://www.iapws.org/relguide/...
1
vote
2
answers
639
views
Compare density of halogen substituted benzene rings
The correct decreasing order of densities of the following compounds is :
(1) (D) > (C) > (B) > (A)
(2) (C) > (D) > (A) > (B)
(3) (C) > (B) > (A) > (D)
(4) (A) > (B) >...
1
vote
0
answers
99
views
Density and partial pressure [closed]
A sample of $\ce{NOBr}$ gas was placed in a rigid flask where it decomposes at $\pu{25 ^\circ C}$ according to the following reaction:
$$\ce{2NOBr(g) <=> 2NO(g) + Br2(g)}$$
At equilibrium, the ...
0
votes
0
answers
27
views
Heat released at constant pressure and temperature and heat released at constant density and temperature
Is there a relation between heat released at constant pressure and temperature and heat released at constant density and temperature?
I was reading some books on propulsion and combustion, and the ...
6
votes
2
answers
2k
views
Why is potassium less dense than sodium?
Potassium has a density of $\pu{0.86g/cm3}$ and sodium has a density of $\pu{0.97g/cm3}$,even though potassium is below sodium and one might expect the alkali metals to exhibit monotonously increasing ...
1
vote
1
answer
310
views
Density and Viscosity for Solution: 80% Liquid Methane CH4 with Solution of 20% Gas Nitrogen N2 on Surface of Titan (the largest moon of Saturn)?
Problem:
Need to estimate the density and dynamic viscosity of such a mixed fluid: 80% Liquid Methane CH4 with solution of 20% Nitrogen Gas N2 with temperature of 94K and pressure of 1,467 hPa (the ...
4
votes
2
answers
3k
views
Relationship between molar mass and density in solids
In ideal gases, it's pretty clear that 1 mole of gas occupies 22.4 L at STP. By knowing this, it's easy to calculate density given molar mass. However, this isn't true for solids. If I know molar mass ...
18
votes
2
answers
2k
views
Why does a 57.15% ABV spirit (ethanol+water) have a density of 923 kg per cubic meter?
According to the UK proof standard, a 100 proof spirit was defined as a spirit with gravity of $\frac{12}{13}$ that of water or $\pu{923 kg m-3}$, which is equivalent to $\mathrm{57.15\% \ ABV}$.
One ...
-4
votes
1
answer
207
views
What factors other than atomic weight affect density of an element? [closed]
Iron, for example, has an atomic weight of 55.845
Whereas hydrogen's atomic weight is 1.008, 1.8% of Irons.
And the density of Hydrogen (at STP) is 0.0899 g/L, 1.14% of of Iron's density of 7.874 g/...
-2
votes
1
answer
48
views
Air bubbles in water [closed]
Problem :
Gas. Density. (Composition)
N2- 0.879 (0.78)
O2-. 1.32 (0.21)
Why air bubbles don't disintegrate in water into different components due to difference in apparent weight (= ...
1
vote
2
answers
2k
views
When calculating the distance between molecules in a solution, is it reasonable to approximate a sphere around each molecule? [closed]
I am attempting to calculate the average distance between molecules in a particular concentration of a solution. My first instinct was to treat the solution as a system of spheres surrounding the ...
0
votes
1
answer
2k
views
Preparing aqueous solution of ethanol [closed]
You need to prepare $\pu{250.0 mL}$ of an aqueous solution of ethanol in the concentration will be $\pu{0.500 mol L-1}$. You have $\pu{100 mL}$ of a commercial solution of ethanol in water $(35.0\% \,...
11
votes
2
answers
10k
views
Density range of table salt?
Does anyone have a reference for the density range of common table salt $(\ce{NaCl})?$
A pure $\ce{NaCl}$ crystal has a density of $\pu{2.16 g/cm^3}.$ However, the salt granules in table salt don't ...
3
votes
1
answer
3k
views
What are the least dense fluids?
This question left me wondering what other very light (condensed) fluids could exist, at any environmental condition.
Obvious candidates for the list are (at their Bp./1 bar)
LH2 (0.07 g/ml)
LHe (0....
1
vote
1
answer
114
views
What is the density of sodium trimethylsilylpropanesulfonate (DSS)?
I tried to look for the density of sodium trimethylsilylpropanesulfonate (DSS) online but could not find anything. Perhaps someone here measured it/knows where it may be found?
0
votes
1
answer
16k
views
Calculate molarity given density and mass percentage [closed]
Problem
Calculate molarity of a solution of $\ce{H2SO4}$ with density $\pu{1.198 g/cm3}$ and containing $27~\%$ mass of $\ce{H2SO4}.$
Answer
My approach
I converted the density to g/l. Then i took ...
7
votes
1
answer
2k
views
Is the density of a two-component mixture always between the densities of its individual components?
There exist eutectic mixtures, in which the freezing point of the mixture is below those of either component of the mixture, i.e., the freezing point of the mixture is not intermediate between that of ...
2
votes
1
answer
387
views
How do I figure out the composition of a material given specific densities?
The Problem
A waste material consists of sand (SG 2.7), a chemical salt (SG 2.1), and a dense plastic (SG 1.4). 200 g of a representative sample from the material is found to have a density of 2300 kg/...