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-1 votes
2 answers
213 views

Which one has a greater dipole moment: benzamide or benzoic acid?

My guess is that, since the relative electronegativities are similar, therefore the difference would arise only due to magnitudes of difference in electronegativities. And hence the strength should be ...
Gajraj Singh's user avatar
1 vote
0 answers
87 views

Quantitatively Calculate Dipole Moment [duplicate]

Recently, I have been reading up on articles relating to the dipole moments of different molecules (specifically this). I see how they can get bond lengths and experimental dipole moments with ...
Prajval K's user avatar
2 votes
0 answers
107 views

Why is the intensity of the IR spectra of IBr higher than that of ICl?

Why is the intensity of the IR spectra of $\ce{IBr}$ higher than that of $\ce{ICl}$? I know that the IR spectra intensities are proportional to the derivative of the dipole moment with internuclear ...
DJA's user avatar
  • 151
-3 votes
2 answers
7k views

Why is CH4 Nonpolar but CH2Cl2 is polar?

I keep reading that the reason why $\ce{CH2Cl2}$ is polar because due to its tetrahedral shape, the dipoles can not cancel each other out but doesn't $\ce{CH4}$ also have tetrahedral shape too? I ...
Epistrophe's user avatar
0 votes
1 answer
157 views

Why must polar molecules be asymetrical? [duplicate]

As I understand, polarity in molecules comes from the difference in electronegativity or the ability of the atoms to attract eletrons so the electrons spend more time or are more probable to gravitate ...
Žan Spehonja's user avatar
1 vote
2 answers
888 views

Which Oxygen atom in HCOOH (formic/methanoic acid) does Carbon donate its electrons to, to obtain a partial positive charge?

I was wondering if the Carbon atom in HCOOH (methanoic/formic acid) forms a positive partial charge by donating its electrons to both the Oxygen atoms, since they both possess a higher ...
bohemian's user avatar
1 vote
1 answer
3k views

Will there be change in electronegativity difference in C-O and C=O?

Is there any change in EN difference in C-O and C=O. If yes, why? Does EN difference change if its bond is changed to single, double, or triple?
Hercules's user avatar
  • 709
8 votes
1 answer
6k views

Why does C=O have a larger dipole moment than C-O?

Why does $\ce{C=O}$ have a larger dipole moment than $\ce{C-O}$? According to me, dipole moment directly depends upon bond length and electronegativity difference. In $\ce{C=O}$ and $\ce{C-O}$, (I ...
Hercules's user avatar
  • 709
0 votes
0 answers
324 views

Why don't I get the same value of percentage ionic character of a particular molecule from different equations?

About the ionic character of a polar covalent compound Pauling gave two equations as [1-$e^{.25(x_a - x_b)}] $% [18$(x_a-x_b)^{1.4}$]% Hanary and Smith gave the equation [$16(x_a-x_b)+3.5(x_a-...
user187604's user avatar
12 votes
2 answers
16k views

Does the dipole moment increase or decrease by increasing the bond length?

It is established the dipole moment is a result of multiplication of the magnitude of charges (Q) and the distance between them (r). What I understand is that when an electron and a proton get closer (...
Eman R. El-laithy's user avatar
5 votes
1 answer
2k views

Dipole Moment of Normal Water vs Heavy Water

The question is in the title itself. My guess: Higher for Normal water. My Reasoning: Internet told me Deuterium is more electronegative than Protium. So, there should be less difference between ...
Amritansh Singhal's user avatar
12 votes
2 answers
2k views

Does 1-bromo-4-chlorobenzene have a permanent dipole moment?

My first thought was there would be a dipole moment as chlorine and bromine are unequal in electronegativity. I have since looked up the electronegativity of both chlorine and bromine through the ...
R. Mauban's user avatar
  • 181
1 vote
1 answer
711 views

Using covalent or ionic radius when calculating dipole moment

When the ionic character of a bond is above 50% should I use ionic radius instead of covalent one when calculating the dipole moment? The formula I have for dipole moment is $\mu = \text{(% ionic ...
user1790813's user avatar
3 votes
1 answer
8k views

Relationship between dipole moment of a molecule and electronegativities of constituent atoms

I want to know if I can calculate the dipole moment of a molecule given the electronegativity values for the atoms comprising it. I think that dipole moments determine the polarity of molecules, so ...
phi2k's user avatar
  • 1,469
4 votes
1 answer
644 views

Bending of water and methanol towards a charged objects

I just had a question about why does water, methanol or any other polar substances tend to bend towards the charged object. I think it is because of a slight dipole dipole movement between the ...
Ethan Hunt's user avatar
15 votes
2 answers
54k views

Why is HCl not considered to have hydrogen bonding?

A molecule that has hydrogen bonding usually follows these two premises. 1.) There is a hydrogen atom involved 2.) Hydrogen must be bonded to a highly electronegative element which are nitrogen ($\ce{...
Luis Averhoff's user avatar