Skip to main content
Search type Search syntax
Tags [tag]
Exact "words here"
Author user:1234
user:me (yours)
Score score:3 (3+)
score:0 (none)
Answers answers:3 (3+)
answers:0 (none)
isaccepted:yes
hasaccepted:no
inquestion:1234
Views views:250
Code code:"if (foo != bar)"
Sections title:apples
body:"apples oranges"
URL url:"*.example.com"
Saves in:saves
Status closed:yes
duplicate:no
migrated:no
wiki:no
Types is:question
is:answer
Exclude -[tag]
-apples
For more details on advanced search visit our help page
Results tagged with
Search options not deleted user 16622

For questions about chemical bonds (ionic/covalent/etc.), their properties (length, energy, angle, etc.) or their relation to other molecular properties (intermolecular forces/dipole moment/etc.). Do not confuse this tag with [lewis-structures], [dipole], [intermolecular-forces], etc.

6 votes

C-N bond lengths in 2-bromo-1,3,5-trinitrobenzene

As I thought this could be interesting because I would have argued the same way as both of you did I have done some geometry optimizations. The final niveau was B3LYP-D3/def2-QZVPP in the gas phase ( …
pH13 - Yet another Philipp's user avatar
2 votes

Is there a definition of rotatable bond?

The IUPAC Gold Book states at least somthing to free rotation: free rotation (hindered rotation, restricted rotation) In a stereochemical context the rotation about a bond is called 'free' when the rotational … The inhibition of rotation of groups about a bond due to the presence of a sufficiently large rotational barrier to make the phenomenon observable on the time scale of the experiment is termed hindered …
pH13 - Yet another Philipp's user avatar
11 votes

What is the highest known bond order?

In the paper that you've mentioned$^{\ast1}$, there is something described, which is called effective bond order ($\mathrm{EBO}$). … Ugalde, Ivan Infante, "Molecules with High Bond Orders and Ultrashort Bond Lengths: $\ce{CrU, MoU,}$ and $\ce{WU}$," Inorg. Chem. 2013, 52(6), 2838–2843 (https://doi.org/10.1021/ic301657c). …
pH13 - Yet another Philipp's user avatar
9 votes
Accepted

Stability of beryllium carbonate

Why and how is this stability maintained? Beryllium carbonate decomposes into Beryllium oxide and Carbon dioxide. $$\ce{BeCO3 <=> BeO + CO2}$$ According to Le Chatelier's principle one simply ha …
pH13 - Yet another Philipp's user avatar
4 votes

The proper explanation for the general formula of the DU?

As every single bond contains two electrons, the amount of all possible bonds is half the amount of all valence electrons, namely $$\sum_{i=1}^N \frac{n_i~v_i}{2}$$ Let's try it with the mass formula …
pH13 - Yet another Philipp's user avatar