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andselisk
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Why is BiCl5 not very stable?

I read this in a textbook:

$\ce{Bi(V)}$ is very unstable and is a good oxidizing agent.

Why does it happen that way? Is it because in $\pu{+5}$ oxidation state $\ce{Bi}$ pulls in more electrons and hence gets reduced fast or there's a different concept?

Also then $\ce{BiCl5}$ should be more stable than $\ce{BiCl3}$ because it's getting the electrons that it needs, which is not true.

Aashi
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