I read this in a textbook -:
Bi(V)$\ce{Bi(V)}$ is very unstable and is a good oxidizing agent.
Why does it happen that way? Is it because in $\pu{+5}$ oxidation state $\ce{Bi}$ pulls in more electrons and hence gets reduced fast or there's a different concept?
Also then $\ce{BiCl5}$ should be more stable than $\ce{BiCl3}$ because it's getting the electrons that it needs, which is not true.