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Also known as banana bond. These kinds of bonds are usually found in small, strained, organic molecules. The simplification of the hybridisation scheme fails for this class of compounds.

33 votes
2 answers
17k views

Sp5 hybridization in cyclopropane?

I have never before heard/read about something as a $sp^5$ hybridization. Today, Henry Rzepa's blog post made me aware of the existance of such a bonding system. That made me search a little bit and I …
pH13 - Yet another Philipp's user avatar
20 votes

Sp5 hybridization in cyclopropane?

Until this post, $\mathrm{sp^1,~sp^2~\text{and}~sp^3}$ meant for me, that the hybrid orbitals would consist from one s orbital and one, two or three p orbitals. I thought of it being so, as this seems …
pH13 - Yet another Philipp's user avatar