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The branch of chemistry that deals with the study of redox reactions and how they can be applied to generate electricity (in electrochemical cells) and to carry out non-spontaneous reactions using electricity (electrolysis).
1
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Carrying out electrolysis of very dilute NaCl for a long time
During the electrolysis of aqueous sodium chloride solution, the products are $\ce{NaOH}$, $\ce{Cl2}$ and $\ce{H2}$ . In this case besides $\ce{Na+}$ and $\ce{Cl–}$ ions we also have $\ce{H+}$ and $\c …
4
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2
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Acid dissociation constant from conductometric data
$\ce{0.007 M}$ aq. solution of anilinium hydrochloride had molar conductivity equal to $\pu{119.4 S cm2 mol-1}$, which became $\pu{103 S cm2 mol-1}$ when a few drops of aniline were added to the solu …
-1
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How do I explain that voltage decreases when increasing the concentration of the cathode in ...
Nernst eqn says that,
$$E_c=E^o_c-\frac{0.059}{n}logQ_c$$.
Now $Q_c = \frac{products}{reactants}$
If I take the cell reaction $\ce{Zn + Cu^2+ -> Zn^2+ + Cu}$,
$Q_c=\frac{[\ce{Zn^2+}](anode)}{[\ce{Cu^2 …