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Enolates are anions derived from the deprotonation of carbonyl compounds. This tag must be used while dealing with the enolates or its derivatives including its resonance forms.

1 vote
2 answers
130 views

Mechanism of deprotection of enol thioether

I was reading some enolate chemistry from Carruthers textbook and came across the selective alkylation of unsymmetrical ketones. The reaction involves blocking one alpha-position of the ketone using a …
Cyclopropanol's user avatar
5 votes
1 answer
288 views

Selective formation of enolates

I saw the following reaction on Modern methods of Organic Synthesis by Carruthers. The reaction is about the selective alkylation of trimethylsilyl enolates, and is shown below. However, I have some …
Cyclopropanol's user avatar