Does the name 4-nitrodiphenylmethane follow the IUPAC rules? It doesn't make sense to me. How can you assign a locant of 4 when your stem name is just methane?

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  • $\begingroup$ I feel like the stem is "diphenylmethane" not just methane $\endgroup$ Commented Sep 18, 2017 at 18:23

1 Answer 1


The preferred IUPAC name for the compound that is given in the question is 1-benzyl-4-nitrobenzene; however, that does not necessarily mean that other names are not in accordance with IUPAC nomenclature.

The name diphenylmethane actually is in accordance with current IUPAC recommendations (see Subsection P- in Nomenclature of Organic Chemistry – IUPAC Recommendations and Preferred Names 2013 (Blue Book)), although the preferred name is 1,1'-methylenedibenzene (see also this answer).

The name diphenylmethane treats the phenyl groups alike as substituents of methane.

If now one of the simple phenyl substituents in diphenylmethane is replaced by a compound 4-nitrophenyl substituent, the analogous name of the resulting compound is (4-nitrophenyl)(phenyl)methane and not ‘4-nitrodiphenylmethane’.

  • $\begingroup$ Ooh, thanks! What if the other phenyl group had been substituted with NO2 para to the methylene substituent? Do I name it bis(4-nitrophenyl)methane? $\endgroup$
    – Acnologia
    Commented Sep 20, 2017 at 2:46

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