6
$\begingroup$

Re-hosting this question from Physics to Chemistry, lightly edited.

Rubies and sapphires are chemically equivalent to the mineral corundum, with the exception of transition metal impurities that impart different colors to the aluminium oxide. Uranium is not a transition metal, but it can be used as a coloration admixture with silicon dioxide, and exists in various oxide forms.

Can uranium be used as a coloration impurity for 1) aluminium oxide based gemstones and/or 2) diamonds? If uranium cannot chemically bond with the substrate, then the ability to produce a consistent heterogeneous mixture, e.g. by suspending uranium oxide dust in molten aluminium oxide during the process of flame fusion would be a satisfactory answer in the affirmative.

$\endgroup$
5
  • 1
    $\begingroup$ Cross-posting is frowned upon, though... $\endgroup$
    – Mithoron
    Commented Jun 1, 2022 at 20:32
  • 2
    $\begingroup$ @Mithoron A mod over at physics suggested here might be better. I see no reason, a priori, it would not be possible to dope the alumina with urania, in moderation. Maybe the result would not be transparent, like uranium glass? $\endgroup$
    – Ed V
    Commented Jun 1, 2022 at 21:01
  • 1
    $\begingroup$ @EdV Yeah, but migration would be proper way to solve it. BTW Uranium is way bigger then Al and that may be a problem. $\endgroup$
    – Mithoron
    Commented Jun 1, 2022 at 21:38
  • $\begingroup$ This actually sounds like an interesting concept. Even if it isn't as easy as it would be for some smaller transition metals, at low concentration is might be interesting. And easy to test. $\endgroup$
    – matt_black
    Commented Jun 1, 2022 at 21:43
  • $\begingroup$ @Mithoron Agreed on both points. Still, it would be interesting to see what happens with a low doping level. $\endgroup$
    – Ed V
    Commented Jun 1, 2022 at 22:14

1 Answer 1

6
$\begingroup$

It's not quite alumina, but uranium(VI) oxide compounds have been used to color glass:

Oxides and uranates of uranium(VI) have been used in the past as yellow ceramic glazes as in Fiesta and to make yellow-green uranium glass.1

enter image description here

Source

But beware:

Both of these applications are abandoned due to concern regarding radioactivity of the uranium.

Cited Reference

  1. Skelcher, Barrie (2002). The Big Book of Vaseline Glass. Atglen, PA: Schiffer Publishing. ISBN 978-0-7643-1474-2.
$\endgroup$
1

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.