Recently I have answered a question "Comparing explosive properties of mercury(II) cyanate and mercury(II) fulminate" where stability of cyanate vs fulminate was discussed. While I was answering that question, I found out that fulminate vs cyanate stability was already pointed out when chemical isomerism was discovered by Liebig and Wohler. They both reported independently and concluded that silver(I) fulminate is explosive while silver(I) cyanate is a stable compound.
I was wondering if chemical isomerism can be applied to discuss mercury(II) cyanate and mercury(II) fulminate stability since it was already applied for corresponding silver salts. Mercury fulminate is well known in explosive industry and is used commercially. OTOH, mercury(II) cyanate is not known/vaguely known as I could not find any information of this compound, So, I assume (incorrectly?) that mercury(II) cyanate doesn't exist and any attempts to isolate the compound would decompose explosively. Moreover, mercury(II) cyanate is one of the decomposition intermediate of mercury(II) fulminate
Questions:
- Does mercury(II) cyanate exist?
- Fulminates are considered unstable and sensitive than cyanates and thus difficult to isolate. So, in this case mercury(II) fulminate should be more unstable and sensitive than mercury(II) cyanate and yet the latter one hasn't been isolated yet. Why?