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Results tagged with pericyclic
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user 35555
For questions concerning all aspects of pericyclic reactions, their use in synthesis, and the orbital analyses used to describe them.
1
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Pericyclic Reaction
PhMe is methylbenzene, better known as toluene.
Toluene is a very common nonpolar, organic solvent. As a simple aromatic solvent, it is preferred over benzene, which is known to be carcinogenic.
In …
- 17.6k
4
votes
Can the Smirnov-Zamkow reaction be described as a pericyclic process?
I was going to write a comment, but I think this is good enough for an answer.
The issue that symmetry rules forbid a [2+2] thermal cycloaddition if the addition is suprafacial-suprafacial.
However, …
- 17.6k
5
votes
Claisen rearrangement in substituted ring
First, consider if this reaction reversible? If so, we'll just form the thermodynamically favorable product. But the temporarily breaking of aromaticity and tautomerization to reform aromaticity sugge …
- 17.6k