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For questions about reactions that favour the formation of one or more stereoisomers.
18
votes
Why do we get slightly more inversion product than retention product in SN1 reaction?
As we know, $\ce{S_N1}$ reaction is stereochemically non specific. This means, that it does not force the formation of one stereoisomer, as $\ce{S_N2}$ does. In $\ce{S_N1}$ reaction, presence of carbe …
9
votes
Accepted
Why is the endo product the major product in a Diels-Alder reaction?
What is the endo-selectivity of Diels-Alder reactions?
If the diene used in the Diels-Alder reaction has asymmetric substituents at the end carbons, and if the dienophile is unsymmetric, then two diff …