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Results tagged with nucleophilicity
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user 16683
For questions involving the nucleophilicity of a chemical species. Not to be confused with "basicity", use the [acid-base] tag instead.
6
votes
Is hydrazine a better nucleophile than ammonia?
A quantitative approach may be found in the Mayr nucleophilicity parameters (Ctrl-F "ammonia" and "hydrazine"):
$$\begin{array}{ccc} \hline
\text{Nucleophile} & N\text{ parameter in }\ce{H2O} & N\text … It also makes sense that the protic solvent water reduces the nucleophilicity of both species.
For more details I suggest reading the articles cited in the database entries. …
- 71.9k
5
votes
Accepted
Effects of Groups on the Nucleophilcity of Nitrogen
Your analysis of "pulls more electron density away" is a bit too simplistic. Both of them are approximately equally electron-withdrawing via the inductive effect, but in terms of resonance, which is t …
- 71.9k