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This tag should be applied to questions relating to the theory, design, techniques or performance of chemical experiments. This includes but is not limited to theoretical structures, expected products, thermal calculations, and empirical analysis. Additional tags should be applied to narrow down the field of research.
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Why is a theoretical titration curve higher than a practical one?
One thing that that has already been mentioned in the comments is the impact of $\ce{CO2}$ on the equilibrium. If you look at the following figure you can see the pH diagram of carbonic acid.
The e …