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5 votes
0 answers
125 views

Is a change in delta-delta-G typically notated as delta-delta-delta-G?

I'm currently writing a research paper, and need to refer to a difference between $\Delta{\Delta}G$s. The naive way to notate this would be $\Delta{\Delta}{\Delta}G$, but that looks cumbersome and ...
Ian Hamilton's user avatar
2 votes
1 answer
80 views

Meaning of the symbol “$\Delta_\mathrm{sub}H^\circ[\ce{I2,s}]$”

One of the back exercises (13(C)) from the book for practice provided at my school asked whether the following relation is true: $\Delta_\mathrm{f}H^\circ(\ce{I2,g}) = \Delta_\mathrm{sub}H^\circ[\ce{...
Aseem Mittal's user avatar
2 votes
0 answers
515 views

Why is U the symbol for lattice energy?

I often see $U$ or even $\Delta U$ being the symbol for lattice energy. Why is that? Does it refer to internal energy?
Quantonium's user avatar
2 votes
1 answer
1k views

Gibbs Free Energy Notation

What's the difference between $G$, $\Delta G$, $\Delta G^\circ$, and $\Delta_\mathrm r G^\circ$? I've seen the first two used interchangably, and seen $G$ specifically referred to as change in Gibbs ...
Vedvart1's user avatar
  • 133
11 votes
1 answer
4k views

Why was a Plimsoll symbol chosen to indicate standard state?

Historically, the Plimsoll symbol (aka Plimsoll line) was created as hull mark that would serve as a ready indicator of whether a ship was overloaded and thus running too low in the water. It was ...
theorist's user avatar
  • 12.3k
36 votes
6 answers
32k views

Why do chemistry and physics have different sign convention in thermodynamics?

In physics class, we write the first law of thermodynamics as $\mathrm dU =\mathrm dQ - \mathrm dW$ and in the physical chemistry class, we write the same law as $\mathrm dU =\mathrm dQ + \mathrm dW$. ...
user avatar
6 votes
3 answers
16k views

kJ per mole or kJ per 2 moles?

From Chemguide: Here is a simple reaction between hydrogen and oxygen to make water: $$\ce{2 H2(g) + O2(g) -> 2 H2O(l)} \quad \Delta_\mathrm{r}H^\circ = \pu{572 kJ mol^-1}$$ First, notice that ...
CowperKettle's user avatar
  • 3,292