-2
$\begingroup$

I'm completely new to chemistry. I can’t personally figure out the basic issues myself, so I’m asking for your help. I became interested in how lithium-ion batteries generally work. As a result, I came to what is the most used material for the anode. This is LixC6. But I don't understand what its structure means, i.e. How do we even understand this? Why are there 3 dies here? What is 'x' in LixC6? Can you explain please. If the question is not clear enough, then let me know, because I really don’t know much about chemistry and I can ask quite stupid questions. 1


References
Image Source - Electronic structure ‘engineering’ in the development of materials for Li-ion and Na-ion batteries. Link
$\endgroup$
0

1 Answer 1

3
$\begingroup$

The three "dies" (if you refer to the graphite planes on the left side of the picture that you provided) are just a convenient way to represent the graphite crystallographic lattice, see the picture below, from Wikipedia.

Graphite crystallographic structure

As for the x, my best guest would be that it represents a statistical fraction of Lithium ion presence. Id est in practice for a given carbon cycle ($\ce{C6}$) it is either 0 or 1, that is we either have $\ce{LiC6}$ or $\ce{C6}$. However, you can average this on your whole lattice. Hence if you have, say $\ce{Li_{0.5}C6}$, it would mean that half the vacancies in your graphite lattice are occupied with a lithium atom. Would you have $\ce{Li_{0.25}C6}$, it would be a quarter of the vacancies, etc.


EDIT: I found confirmation of this in [1], which also provided a figure similar to yours.

Li-Ion battery principle


References

[1] DM1 - Le lithium dans les accumulateurs Li-ion (Centrale PSI 2015), Archive

$\endgroup$
3
  • 1
    $\begingroup$ For future reference: for the body of questions, answers, and comments, chemistry.se offers to use mhchem as a comfortable method to add chemical equations. $\endgroup$
    – Buttonwood
    Commented Nov 30, 2023 at 17:27
  • $\begingroup$ @Buttonwood, I must admit that I do not see the interest of your 'edit' here... I mean: is this not completely equivalent to write $\ce{C6}$ or C$_6$ (first one written with ce, second one with basic LaTeX command)? I get the point that in case of long equations, using mhchem would proove meaningful, but in more basic cases I simply do not see the point... Am I missing something here? (I may be completely misled) $\endgroup$
    – mranvick
    Commented Dec 1, 2023 at 15:26
  • 2
    $\begingroup$ It was for consistency in the representation and to ease of reading without JS enabled. $\endgroup$
    – Buttonwood
    Commented Jan 5 at 14:04

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.