1
$\begingroup$

I found a useful (though simplified) scheme illustrating the energies of atomic orbitals, in crescent order:

enter image description here

I wonder if there was an analogous (simplified) scheme or rule for molecular orbitals, at least for diatomic homonuclear molecules, for which the electronic state is given by the so-called molecular term symbol

$$\displaystyle {}^{2S+1}\!\Lambda _{\Omega ,(g/u)}^{(+/-)}$$

where

${\displaystyle S}$ is the total spin quantum number

${\displaystyle \Lambda }$ is the projection of the orbital angular momentum along the internuclear axis

${\displaystyle \Omega }$ is the projection of the total angular momentum along the internuclear axis

${\displaystyle g/u}$ indicates the symmetry or parity with respect to inversion through a centre of symmetry

${\displaystyle +/-}$ is the reflection symmetry along an arbitrary plane containing the internuclear axis

Such scheme or rule would justify for instance the following succession:

$$\sigma_g(1s)<\sigma_u(1s)<\sigma_g(2s)<\sigma_u(2s)<\pi_u(2p) <\sigma_g(2p)<\dots$$

$\endgroup$

1 Answer 1

1
$\begingroup$

I don't know if that's exactly what you meant. But, how about this from https://pressbooks.online.ucf.edu/:

Chemistry Fundamentals by Dr. Julie Donnelly, Dr. Nicole Lapeyrouse, and Dr. Matthew Rex

enter image description here

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.