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Why do we not need $\ce{H2SO4}$ as an acid catalyst for the di-nitration of veratrole?

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Why does the 2nd nitro group go to positions 4 or 5, following the directing effects of the methoxy-group? Doesn't the first nitro group, that has been substituted intoonto the compound, have any effect on its position?

Why do we not need $\ce{H2SO4}$ as acid catalyst for di-nitration of veratrole?

Why does the 2nd nitro group go to positions 4 or 5, following the directing effects of the methoxy-group? Doesn't the first nitro group, that has been substituted into the compound, have any effect on its position?

Why do we not need $\ce{H2SO4}$ as an acid catalyst for the di-nitration of veratrole?

enter image description here

Why does the 2nd nitro group go to positions 4 or 5, following the directing effects of the methoxy-group? Doesn't the first nitro group, that has been substituted onto the compound, have any effect on its position?

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Dinitration Why is nitration of veratrole specific in these positions?

1)WhyWhy do we not need H2SO4$\ce{H2SO4}$ as acid catalyst for dinitrationdi-nitration of veratroleveratrole?

2)and whyWhy does the 2nd nitro groupsgroup go to positions 4 or 5, following the directing effects of the MeOmethoxy- groupgroup? DoesntDoesn't the first nitro group, that has been substituted into the compound, have any effect on its position?

Dinitration of veratrole

1)Why do we not need H2SO4 as acid catalyst for dinitration of veratrole?

2)and why does the 2nd nitro groups go to positions 4 or 5, following the directing effects of the MeO- group? Doesnt the first nitro group that has been substituted into the compound have any effect on its position?

Why is nitration of veratrole specific in these positions?

Why do we not need $\ce{H2SO4}$ as acid catalyst for di-nitration of veratrole?

Why does the 2nd nitro group go to positions 4 or 5, following the directing effects of the methoxy-group? Doesn't the first nitro group, that has been substituted into the compound, have any effect on its position?

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Dinitration of veratrole

1)Why do we not need H2SO4 as acid catalyst for dinitration of veratrole?

2)and why does the 2nd nitro groups go to positions 4 or 5, following the directing effects of the MeO- group? Doesnt the first nitro group that has been substituted into the compound have any effect on its position?