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For questions concerning all aspects of pericyclic reactions, their use in synthesis, and the orbital analyses used to describe them.
2
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0
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Can endo and exo products occur when the diene is not cyclic?
I have always thought that the diene needs to be cyclic for there to be endo and exo products. Perhaps, I formed this impression because most textbook examples that are used to illustrate the concept …
8
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2
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Identification of endo and exo products in this Diels-Alder reaction
This synthesis example is shown in the book Cycloaddition Reactions in Organic Synthesis by S. Kobayashi and K. A. Jorgensen (link), on p. 15:
8 is a chiral catalyst, which can be ignored, in the co …