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Tyberius
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Is the existence of chirality center equivalent to chiral?

To make my question more clear, I want to ask two questions:

  1. Is it possible for molecule to be achiral even though molecule has chirality center?
  1. Is it possible for molecule to be chiral even though molecule doesn't have chirality center?

I thought of these questions because the definitions of chiral center and chiral do not have a one to one correspondence.

A chiral center is defined by carbon having four different ligands around it and chiral is defined by a compound being non-superimposable with its mirror image. They are quite related, but I think there will be counterexamples that satisfy one condition but not satisfy the other one.

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