The expression for the mass-transfer limited current $i$ is given by $i = nFAmC$.
where $C$ [mol cm$^{-3}$$C~[\mathrm{mol\, cm^{-3}}$] represents the concentration of the electrochemically active species that gets converted at the electrode; if the entire analyte gets converted, then $C$ is equal to the initial bulk concentration of the analyte.
I am confused as to what electrochemically active species mean? Is that just saying the ions in solution? Or is it the oxidized ion and the reduced ion?