Timeline for Why is the endo product the major product in a Diels-Alder reaction?
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| Jan 17, 2022 at 5:35 | vote | accept | user1 | ||
| S Mar 6, 2021 at 16:39 | history | bounty ended | NotEvans. | ||
| S Mar 6, 2021 at 16:39 | history | notice removed | NotEvans. | ||
| Mar 4, 2021 at 21:24 | answer | added | S R Maiti | timeline score: 9 | |
| S Feb 28, 2021 at 19:03 | history | bounty started | NotEvans. | ||
| S Feb 28, 2021 at 19:03 | history | notice added | NotEvans. | Canonical answer required | |
| Jan 30, 2019 at 11:31 | history | protected | andselisk♦ | ||
| Sep 18, 2018 at 4:36 | comment | added | Len_sprague | Both the explanation of secondary orbital interactions (SOI) and extra configurational strain in exo through transition states (and along reaction coordinates overall) result in endo being favored regularly. Diels-Alder's "endo rule" was born from experiment, and is also not actually a rigid "rule" (see tuning endo/exo selectivity in the two papers, and in the stack exchange related question by @ron), and is only intended as a tool in predicting expected products. Fernandez & Bickelhaupt's work is probably the most thorough description to date, supporting expt & previous theory to some degree. | |
| Apr 12, 2018 at 2:17 | history | bumped | CommunityBot | This question has answers that may be good or bad; the system has marked it active so that they can be reviewed. | |
| Mar 13, 2018 at 1:49 | history | bumped | CommunityBot | This question has answers that may be good or bad; the system has marked it active so that they can be reviewed. | |
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| Nov 13, 2017 at 0:32 | history | bumped | CommunityBot | This question has answers that may be good or bad; the system has marked it active so that they can be reviewed. | |
| Oct 13, 2017 at 23:37 | answer | added | Raul Luciano | timeline score: -1 | |
| Oct 13, 2017 at 22:08 | history | edited | orthocresol |
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| Apr 13, 2017 at 12:57 | history | edited | CommunityBot |
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| Dec 10, 2016 at 15:28 | comment | added | ron | related: Endo rule and stereoselectivity in the Diels-Alder reaction | |
| Dec 10, 2016 at 12:56 | history | tweeted | twitter.com/StackChemistry/status/807569682521853955 | ||
| Dec 10, 2016 at 3:49 | comment | added | orthocresol | Your textbook's description is probably a watered-down version of the secondary orbital interactions, which have traditionally been the explanation for the endo rule (see any other org chem textbook for diagrams). Good find on the paper though. | |
| Dec 10, 2016 at 3:47 | history | edited | orthocresol |
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| Dec 10, 2016 at 3:30 | history | edited | user1 | CC BY-SA 3.0 |
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| Dec 10, 2016 at 3:25 | history | asked | user1 | CC BY-SA 3.0 |