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Timeline for Nitric Oxide Dimerization

Current License: CC BY-SA 3.0

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Aug 17, 2014 at 5:52 history edited Martin - マーチン CC BY-SA 3.0
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Aug 15, 2014 at 22:51 vote accept Dissenter
Aug 15, 2014 at 22:04 answer added ron timeline score: 4
Aug 15, 2014 at 22:03 comment added Dissenter Oh wait nvm I see it after I drew out the diagram; the 100 degree bond angles deviate from the usual sp3 hybridized bond angle; this suggests that the oxygens may be interacting with each other and closing up the bond angle from 109.5 degrees. Are there really available orbitals on the oxygens to do this/
Aug 15, 2014 at 22:02 comment added Dissenter What does bond angle suggest about the nature of the bond, exactly? How can you conclude that there are O-O interactions based on angles?
Aug 15, 2014 at 22:02 history edited Dissenter CC BY-SA 3.0
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Aug 15, 2014 at 21:59 comment added permeakra >This is the molecular orbital diagram for nitric oxide || It shows oxygen having orbitals with higher energy, which is obviously wrong. Please, check. As for the question, the $\ce{ONN}$ angle in N2O2 is ~100, so I would say the nature of the bond is debatable. While antibonding orbital obviously is shifted towards atom with higher initial orbitals, the angles suggests partial O-O or O-N interactions as well.
Aug 15, 2014 at 21:24 history edited Dissenter CC BY-SA 3.0
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Aug 15, 2014 at 21:12 history asked Dissenter CC BY-SA 3.0