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I need to propose a 2-step reaction mechanism for the following reaction: $$2NO_2Br\rightarrow 2NO_2+Br$$$$\ce{2NO2Br -> 2NO2 +Br}$$ And prove the mechanism is consistent with: $$v=k[NO_2Br]^2$$$$v=k[\ce{NO2Br}]^2$$ For the mechanism to be consistent with the rate equation, the first equation would have to be the limiting one and also be in this form: $$2NO_2Br\rightarrow Products$$$$\ce{2NO_2Br -> Products}$$ I've tried using: $$2NO_2Br\rightarrow N_2O_4+Br_2$$$$\ce{2NO2Br -> N2O4 +Br2}$$ $$N_2O_4\rightarrow 2NO_2$$$$\ce{N2O4 -> 2NO2}$$ But the problem with this mechanism is that N2O4$\ce{N2O4}$ is not unstable enough to be consumed immediately. Any help with this problem?
Would also appreciate some advice on proposing reaction mechanisms. Thank you.

I need to propose a 2-step reaction mechanism for the following reaction: $$2NO_2Br\rightarrow 2NO_2+Br$$ And prove the mechanism is consistent with: $$v=k[NO_2Br]^2$$ For the mechanism to be consistent with the rate equation, the first equation would have to be the limiting one and also be in this form: $$2NO_2Br\rightarrow Products$$ I've tried using: $$2NO_2Br\rightarrow N_2O_4+Br_2$$ $$N_2O_4\rightarrow 2NO_2$$ But the problem with this mechanism is that N2O4 is not unstable enough to be consumed immediately. Any help with this problem?
Would also appreciate some advice on proposing reaction mechanisms. Thank you.

I need to propose a 2-step reaction mechanism for the following reaction: $$\ce{2NO2Br -> 2NO2 +Br}$$ And prove the mechanism is consistent with: $$v=k[\ce{NO2Br}]^2$$ For the mechanism to be consistent with the rate equation, the first equation would have to be the limiting one and also be in this form: $$\ce{2NO_2Br -> Products}$$ I've tried using: $$\ce{2NO2Br -> N2O4 +Br2}$$ $$\ce{N2O4 -> 2NO2}$$ But the problem with this mechanism is that $\ce{N2O4}$ is not unstable enough to be consumed immediately. Any help with this problem?
Would also appreciate some advice on proposing reaction mechanisms. Thank you.

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jcgereda
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2-step reaction mechanism for the decomposition of NO2Br

I need to propose a 2-step reaction mechanism for the following reaction: $$2NO_2Br\rightarrow 2NO_2+Br$$ And prove the mechanism is consistent with: $$v=k[NO_2Br]^2$$ For the mechanism to be consistent with the rate equation, the first equation would have to be the limiting one and also be in this form: $$2NO_2Br\rightarrow Products$$ I've tried using: $$2NO_2Br\rightarrow N_2O_4+Br_2$$ $$N_2O_4\rightarrow 2NO_2$$ But the problem with this mechanism is that N2O4 is not unstable enough to be consumed immediately. Any help with this problem?
Would also appreciate some advice on proposing reaction mechanisms. Thank you.