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V.G
  • Member for 4 years, 5 months
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Balancing redox reactions
Do you know how to calculate the $n$ or the $z$ factor of the reaction? And the change in the oxidation states of the reactant species?
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Confusion in comparing the contribution of resonating structures to resonance hybrid
@AdityaRoychowdhury I agree. I didn't notice that part, thanks for pointing it out.
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Confusion in comparing the contribution of resonating structures to resonance hybrid
What I mean to say is, in the original question that you have asked, there is no role of inductive effect. If situation arises, that we also need to see the inductive effect also, then we will see it. I think this would be helpful.
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Confusion in comparing the contribution of resonating structures to resonance hybrid
Here, you will use inductive effect, as the alkyl group has more electron releasing tendency, so it will have less -M effect as compared to $\ce{-CHO}$. Wikipedia is a good place to read about it.
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Confusion in comparing the contribution of resonating structures to resonance hybrid
While comparing the stability among carbocations and carbanions, we use inductive effect because it gives the idea of electron density on that species, electron deficient species would get stabilsed if it is attached to ERG, similarly carbanions will get stabilised if they are attached to EWG. When comparing "resonating structures", we have to chose which among them is more stable, for which we have different parameters like seeing if their octet is complete, no. of $\pi$ bonds, charge separation, negative charge on EN atom and so on... inductive effect is not relevant here.
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Confusion in comparing the contribution of resonating structures to resonance hybrid
Why should inductive effect be considered for resonating structures? It has to do with stability, the one which is more stable will have more contribution in resonating structures. Inductive effect is an entirely different thing than stability.
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Comparing of melting point of dibromo p-xylenes
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Identification of the organic compound
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3-propyl-penta-1,3-diene vs 3-ethylidene-hex-1-ene
@Loong Can you provide a source from where I can refer nomencluature rules, I don't have access to the blue book.
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Why can toluene be chlorinated at either the benzylic position or the ring depending on the conditions?
After dichlorination on methyl group of toluene, why can't a third chlorine attach on the benzylic carbon?
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