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Oscar Lanzi
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Oxygen can be bonded with 180° bond angles in perovskite structures, such as silicate minerals formed deep in Earth's mantle (the perovskite form of calcium silicate has been identified at Earth's surface by being trapped under internal pressure in diamonds). Such minerals have octahedrally coordinated silicon atoms connected by linearly two-coordinate oxygens, with the empirical formula $\ce{MSiO3}$.

Since the silicon in this silicate-perovskite structure is a $p$-block element and yet octahedrally coordinated, the covalent bonds to it are shared over multiple atoms and thus each silicon-oxygen linkage is partially ionic (cf. $\ce{SF6}$).

Oscar Lanzi
  • 62.5k
  • 4
  • 96
  • 187