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Nicolau Saker Neto
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Check out the NIST database for electronic configurations for atoms and ions in the gas phase. If you play around a bit, you will find that yes, some ionizations will not follow the expected trends from the aufbau principle. For example, search for rhenium and compare the configurations between $\ce{Rh^{11+}}$$\ce{Re^{11+}}$ and $\ce{Rh^{17+}}$$\ce{Re^{17+}}$, and you'll see some of them are unexpected (and rather hard to explain). Osmium shows an anomaly going from $\ce{Os^{+}}$ to $\ce{Os^{2+}}$. There are other elements with ions containing aufbau anomalies, but I can't remember many from the top of my head.

Check out the NIST database for electronic configurations for atoms and ions in the gas phase. If you play around a bit, you will find that yes, some ionizations will not follow the expected trends from the aufbau principle. For example, search for rhenium and compare the configurations between $\ce{Rh^{11+}}$ and $\ce{Rh^{17+}}$, and you'll see some of them are unexpected (and rather hard to explain). There are other elements with ions containing aufbau anomalies, but I can't remember many from the top of my head.

Check out the NIST database for electronic configurations for atoms and ions in the gas phase. If you play around a bit, you will find that yes, some ionizations will not follow the expected trends from the aufbau principle. For example, search for rhenium and compare the configurations between $\ce{Re^{11+}}$ and $\ce{Re^{17+}}$, and you'll see some of them are unexpected (and rather hard to explain). Osmium shows an anomaly going from $\ce{Os^{+}}$ to $\ce{Os^{2+}}$. There are other elements with ions containing aufbau anomalies, but I can't remember many from the top of my head.

Source Link
Nicolau Saker Neto
  • 29.2k
  • 4
  • 96
  • 146

Check out the NIST database for electronic configurations for atoms and ions in the gas phase. If you play around a bit, you will find that yes, some ionizations will not follow the expected trends from the aufbau principle. For example, search for rhenium and compare the configurations between $\ce{Rh^{11+}}$ and $\ce{Rh^{17+}}$, and you'll see some of them are unexpected (and rather hard to explain). There are other elements with ions containing aufbau anomalies, but I can't remember many from the top of my head.