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Nicolau Saker Neto
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Now, since the reaction rate depends on selecting the fastest route, you shouldn't expect any of the steps in it to contain some very huge bottleneck, such as requiring six molecules to react simultaneously; there would likely be a slightly different route, perhaps with more steps, but in which each step doesn't involve so many molecules interacting at once, and hence being a faster route. Because of this, it turns out that most of the fastest reaction pathways involve slowest steps that very rarely depend on more than two molecules at once. Most reactions which can be modeled simply like this therefore have rate equations of the type $r=k[A]$, $r=k[A]^2$, $r=k[A][B]$ or even $r=k$. Few reactions rates are of the third order, of the type $r=k[A]^3$, $r=k[A]^2[B]$, $r=k[A][B][C]$ or similar. I don't know of any reaction that goes as $r=k[A]^3$ specifically. Fourth order reaction rates are so rare that they are the focus of research when found. I don't expect anyone to know a fifth order reaction.

At the end of the day, kinetic theory is hard enough that reaction kinetics end up being determined simply by parameter fitting from experiments. Even if the underlying reaction mechanism is not completely understood, if a fit of the type $r=k[A]^{3/2}[B]^{-1}$ happens to be good, then so be it. Reactions which have been studied in depth are significantly more complex, such as the misleading simplicity of the reaction between hydrogen and bromine.

Edit: I don't know why I didn't search for a fifth order reaction rate! Turns out some exist, such as this one. The reaction rate is of the type $r=k[A][B]^4$, so you could have an example where $\frac{d[B]}{dt}=k[B]^4$.

Now, since the reaction rate depends on selecting the fastest route, you shouldn't expect any of the steps in it to contain some very huge bottleneck, such as requiring six molecules to react simultaneously; there would likely be a slightly different route, perhaps with more steps, but in which each step doesn't involve so many molecules interacting at once, and hence being a faster route. Because of this, it turns out that most of the fastest reaction pathways involve slowest steps that very rarely depend on more than two molecules at once. Most reactions which can be modeled simply like this therefore have rate equations of the type $r=k[A]$, $r=k[A]^2$, $r=k[A][B]$ or even $r=k$. Few reactions rates of the third order, of the type $r=k[A]^3$, $r=k[A]^2[B]$, $r=k[A][B][C]$ or similar. I don't know of any reaction that goes as $r=k[A]^3$ specifically. Fourth order reaction rates are so rare that they are the focus of research when found. I don't expect anyone to know a fifth order reaction.

At the end of the day, kinetic theory is hard enough that reaction kinetics end up being determined simply by parameter fitting from experiments. Even if the underlying reaction mechanism is not completely understood, if a fit of the type $r=k[A]^{3/2}[B]^{-1}$ happens to be good, then so be it. Reactions which have been studied in depth are significantly more complex, such as the misleading simplicity of the reaction between hydrogen and bromine.

Now, since the reaction rate depends on selecting the fastest route, you shouldn't expect any of the steps in it to contain some very huge bottleneck, such as requiring six molecules to react simultaneously; there would likely be a slightly different route, perhaps with more steps, but in which each step doesn't involve so many molecules interacting at once, and hence being a faster route. Because of this, it turns out that most of the fastest reaction pathways involve slowest steps that very rarely depend on more than two molecules at once. Most reactions which can be modeled simply like this therefore have rate equations of the type $r=k[A]$, $r=k[A]^2$, $r=k[A][B]$ or even $r=k$. Few reactions rates are of the third order, of the type $r=k[A]^3$, $r=k[A]^2[B]$, $r=k[A][B][C]$ or similar. I don't know of any reaction that goes as $r=k[A]^3$ specifically. Fourth order reaction rates are so rare that they are the focus of research when found. I don't expect anyone to know a fifth order reaction.

At the end of the day, kinetic theory is hard enough that reaction kinetics end up being determined simply by parameter fitting from experiments. Even if the underlying reaction mechanism is not completely understood, if a fit of the type $r=k[A]^{3/2}[B]^{-1}$ happens to be good, then so be it. Reactions which have been studied in depth are significantly more complex, such as the misleading simplicity of the reaction between hydrogen and bromine.

Edit: I don't know why I didn't search for a fifth order reaction rate! Turns out some exist, such as this one. The reaction rate is of the type $r=k[A][B]^4$, so you could have an example where $\frac{d[B]}{dt}=k[B]^4$.

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Nicolau Saker Neto
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I hope you've seen the rate equation page on Wikipedia as it contains a good deal of the mathematics in several examples of reactions. You should also be interested in the reaction order page (you can find examples here of reactions with fraction or negative order with respect to some reagents).

Now, since the reaction rate depends on selecting the fastest route, you shouldn't expect any of the steps in it to contain some very huge bottleneck, such as requiring six molecules to react simultaneously; there would likely be a slightly different route, perhaps with more steps, but in which each step doesn't involve so many molecules interacting at once, and hence being a faster route. Because of this, it turns out that most of the fastest reaction pathways involve slowest steps that very rarely depend on more than two molecules at once. Most reactions which can be modeled simply like this therefore have rate equations of the type $r=k[A]$, $r=k[A]^2$, $r=k[A][B]$ or even $r=k$. Few reactions rates of the third order, of the type $r=k[A]^3$, $r=k[A]^2[B]$, $r=k[A][B][C]$ or similar. I don't know of any reaction that goes as $r=k[A]^3$ specifically. Fourth order reaction rates are so rare that they are the focus of research when foundfocus of research when found. I don't expect anyone to know a fifth order reaction.

I hope you've seen the rate equation page on Wikipedia as it contains a good deal of the mathematics in several examples of reactions. You should also be interested in the reaction order page.

Now, since the reaction rate depends on selecting the fastest route, you shouldn't expect any of the steps in it to contain some very huge bottleneck, such as requiring six molecules to react simultaneously; there would likely be a slightly different route, perhaps with more steps, but in which each step doesn't involve so many molecules interacting at once, and hence being a faster route. Because of this, it turns out that most of the fastest reaction pathways involve slowest steps that very rarely depend on more than two molecules at once. Most reactions which can be modeled simply like this therefore have rate equations of the type $r=k[A]$, $r=k[A]^2$, $r=k[A][B]$ or even $r=k$. Few reactions rates of the third order, of the type $r=k[A]^3$, $r=k[A]^2[B]$, $r=k[A][B][C]$ or similar. I don't know of any reaction that goes as $r=k[A]^3$ specifically. Fourth order reaction rates are so rare that they are the focus of research when found. I don't expect anyone to know a fifth order reaction.

I hope you've seen the rate equation page on Wikipedia as it contains a good deal of the mathematics in several examples of reactions. You should also be interested in the reaction order page (you can find examples here of reactions with fraction or negative order with respect to some reagents).

Now, since the reaction rate depends on selecting the fastest route, you shouldn't expect any of the steps in it to contain some very huge bottleneck, such as requiring six molecules to react simultaneously; there would likely be a slightly different route, perhaps with more steps, but in which each step doesn't involve so many molecules interacting at once, and hence being a faster route. Because of this, it turns out that most of the fastest reaction pathways involve slowest steps that very rarely depend on more than two molecules at once. Most reactions which can be modeled simply like this therefore have rate equations of the type $r=k[A]$, $r=k[A]^2$, $r=k[A][B]$ or even $r=k$. Few reactions rates of the third order, of the type $r=k[A]^3$, $r=k[A]^2[B]$, $r=k[A][B][C]$ or similar. I don't know of any reaction that goes as $r=k[A]^3$ specifically. Fourth order reaction rates are so rare that they are the focus of research when found. I don't expect anyone to know a fifth order reaction.

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Nicolau Saker Neto
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How thoughtful of you to include chemistry in your differential equations course! We appreciate your effort, especially going the extra mile to make it realistic.

I hope you've seen the rate equation page on Wikipedia as it contains a good deal of the mathematics in several examples of reactions. You should also be interested in the reaction order page.

Let me do a quick recap on basic chemical kinetics theory. Consider the general reaction equation:

$$\ce{a\ A + b\ B + c\ C + d\ D + ... \longrightarrow w\ W + x\ X + y\ Y + z\ Z + ...}$$

, where uppercase letters indicate different molecules in a gas or solution, and lowercase letters indicate the stoichiometric coefficients (negative for the reactants, positive for the products). Naively, we can assume the reaction happens because, while the molecules are jostling about, at some point all of the reactants ($a$ molecules of $\ce{A}$, $b$ molecules of $\ce{B}$, $c$ molecules of $\ce{C}$, etc.) will bump into each other all at the same time and undergo reaction. If you think of collisions as independent events with a probability of happening proportional to the concentration of each species, then it isn't too hard to understand that the frequency with which reactions happens is proportional to $[A]^a[B]^b[C]^c[D]^d...$, and so the rate equation for the reaction would be:

$$r=k[A]^a[B]^b[C]^c[D]^d...$$

, where r is the reaction rate and k is a proportionality constant. The consumption or production rate for any species $\Gamma$ with stoichiometric coefficient $\gamma$ is trivially related to the reaction rate by:

$$\frac{d\Gamma}{dt}=\gamma r$$

However, experimentally things aren't so simple (fortunately for nature, unfortunately for our minds). A reaction that requires the simultaneous collision of many molecules would be highly unlikely, meaning that it would happen very, very slowly. Even so, experimentally we observe many reactions that involve a large amount of molecules. For example, the combustion of cyclohexane in air is formally given by the equation:

$$\ce{C6H12 + 9 O2 → 6CO2 + 6 H2O}$$

If the reaction really required ten molecules to bump into eachother at the same time with sufficient energy and in the right geometry, then this reaction probably could not happen in air, as oxygen would be too rarefied to compensate the extremely low proportionality constant k for a single-step reaction. In actuality, a gaseous mix of cyclohexane and air can react so fast as to cause an explosion, converting all the reactants into products in a miniscule fraction of a second. Clearly something is wrong.

It turns out the assumption that reactions occur in one step is incorrect in general. Usually, there is more than one step involved, and indeed there generally is more than one path from reactants to products. The speed at which a reaction occurs is really described by considering all paths at once, with all their steps, and adding their contributions (like a start and end point in a complex tree diagram). In general this is pretty difficult and unnecessarily complex. It is often a reasonable approximation to model the reaction by selecting only the fastest route from reactants to products, and the reaction rate is bottlenecked by the slowest step of the fastest route, which becomes responsible for determining the rate equation.

Now, since the reaction rate depends on selecting the fastest route, you shouldn't expect any of the steps in it to contain some very huge bottleneck, such as requiring six molecules to react simultaneously; there would likely be a slightly different route, perhaps with more steps, but in which each step doesn't involve so many molecules interacting at once, and hence being a faster route. Because of this, it turns out that most of the fastest reaction pathways involve slowest steps that very rarely depend on more than two molecules at once. Most reactions which can be modeled simply like this therefore have rate equations of the type $r=k[A]$, $r=k[A]^2$, $r=k[A][B]$ or even $r=k$. Few reactions rates of the third order, of the type $r=k[A]^3$, $r=k[A]^2[B]$, $r=k[A][B][C]$ or similar. I don't know of any reaction that goes as $r=k[A]^3$ specifically. Fourth order reaction rates are so rare that they are the focus of research when found. I don't expect anyone to know a fifth order reaction.

At the end of the day, kinetic theory is hard enough that reaction kinetics end up being determined simply by parameter fitting from experiments. Even if the underlying reaction mechanism is not completely understood, if a fit of the type $r=k[A]^{3/2}[B]^{-1}$ happens to be good, then so be it. Reactions which have been studied in depth are significantly more complex, such as the misleading simplicity of the reaction between hydrogen and bromine.