The most common thingprocess that can cause proton signalboth peak broadening and an increase in the value of a peak integral value is exchange broadeningexchange broadening between two different protons that are slowly (on. The following diagram represents a typical case where the nmr timescale)protons in water are exchanging with the hydroxyl proton in your sample. For example, if you have an alcohol $\ce{-OH}$ signal, but there.
If the rate of exchange is also some water in your samplefast on the nmr timescale, then the protons will exchange between these two environments. The observed signal will be broadeneda single, sharp peak of increased amplitude and have a larger integral value than expectedweighted average of the individual chemical shifts is observed. Also If the rate of exchange is slow compared to the nmr timescale, then two distinct peaks, both with accurate integrals, are seen. In the positioncase where the rate of exchange is comparable to the timescale of the nmr experiment, then a broadened peak will besignal with integral intensity equal to the two combined signals and located at a weighted average of the chemical shifts for the two independentseparate signals is observed.
If adventitiousOne way you can test to see if a small amount of water in your sample is the culprit, you can add is as follows. Add a small amount of $\ce{H2O}$ to your sample and see if the peak for your sample shifts to a new location and the integral value further increases.