Timeline for Number of diastereomer pairs of 1,3-dichloro-1,2,3-triphenylpropane
Current License: CC BY-SA 3.0
14 events
when toggle format | what | by | license | comment | |
---|---|---|---|---|---|
Aug 9, 2020 at 6:53 | comment | added | Mathew Mahindaratne | CIP-assignments of A and C are incorrect. Actually, they are correct assignments of E and G. I appreciate if you correct them ASAP. | |
Mar 27, 2017 at 16:53 | comment | added | jerepierre | @orthocresol I've changed it to reflect that C2 may or may not be in a chiral environment. | |
Mar 27, 2017 at 16:46 | history | edited | jerepierre | CC BY-SA 3.0 |
changed to reflect understanding of "chirotopic"
|
Mar 27, 2017 at 16:17 | comment | added | orthocresol | As for the r/s notation, future visitors to this question may be interested in: What does lowercase r-s notation mean? and IUPAC name for 1,2,3-trichlorocyclopropane? where the notation is explained in detail with reference to the Blue Book. | |
Mar 27, 2017 at 16:13 | comment | added | orthocresol | As far as I can tell (by reading Anslyn/Dougherty section 6.3.3) C-2 is chirotopic only in those isomers which are chiral, i.e. B and F. In the meso compounds A and C, C-2 lies within the plane of symmetry and is therefore achirotopic. So, both of you are correct. :) | |
Mar 27, 2017 at 15:58 | history | rollback | jerepierre |
Rollback to Revision 3
|
|
Oct 15, 2016 at 19:12 | history | edited | EJC | CC BY-SA 3.0 |
added 5 characters in body
|
Oct 15, 2016 at 19:11 | comment | added | EJC | Carbon 2 is achirotopic, not chirotopic and it is called a stereocenter as it can have r/s configuration. It is not strictly a chiral center because two attached groups differ only by their configurations. | |
Nov 26, 2015 at 16:44 | history | edited | user7951 | CC BY-SA 3.0 |
markup/typography corrected
|
Nov 3, 2014 at 19:33 | vote | accept | yolo123 | ||
Nov 3, 2014 at 19:27 | history | edited | jerepierre | CC BY-SA 3.0 |
edited body
|
Nov 3, 2014 at 19:07 | vote | accept | yolo123 | ||
Nov 3, 2014 at 19:33 | |||||
Nov 3, 2014 at 19:03 | comment | added | yolo123 | Hmm. The solutions said the answer was two. Like my guess... I conclude that the solutions is mistaken. | |
Nov 3, 2014 at 17:31 | history | answered | jerepierre | CC BY-SA 3.0 |