Skip to main content
added 1 character in body
Source Link
DavePhD
  • 41k
  • 2
  • 91
  • 189

Just after XeF2 was discovered, D. F. Smith published a short communication Xenon Difluoride J. Chem. Phys. 38, 270 (1963) mentioning the electronic structure of your second drawing.

Smith conducted infrared spectroscopy of XeF2 and wrote:

enter image description here

Then C. A. Coulson published The nature of the bonding in xenon fluorides and related molecules J. Chem. Soc., 1964, 1442-1454, which considered the validity of four models (plus some sub-models) of XeF2 bonding.

Coulson adds more resonance structurestructures in addition to the two mentioned by Smith, including a purely ionic F- Xe2+ F- resonance structure.

For a more recent article on the topic, see The essential role of charge-shift bonding in hypervalent prototype XeF2 Nature Chemistry 5, 417–422 (2013). (official link)

Overall, ionic contributions do need to be considered.

Just after XeF2 was discovered, D. F. Smith published a short communication Xenon Difluoride J. Chem. Phys. 38, 270 (1963) mentioning the electronic structure of your second drawing.

Smith conducted infrared spectroscopy of XeF2 and wrote:

enter image description here

Then C. A. Coulson published The nature of the bonding in xenon fluorides and related molecules J. Chem. Soc., 1964, 1442-1454, which considered the validity of four models (plus some sub-models) of XeF2 bonding.

Coulson adds more resonance structure in addition to the two mentioned by Smith, including a purely ionic F- Xe2+ F- resonance structure.

For a more recent article on the topic, see The essential role of charge-shift bonding in hypervalent prototype XeF2 Nature Chemistry 5, 417–422 (2013). (official link)

Overall, ionic contributions do need to be considered.

Just after XeF2 was discovered, D. F. Smith published a short communication Xenon Difluoride J. Chem. Phys. 38, 270 (1963) mentioning the electronic structure of your second drawing.

Smith conducted infrared spectroscopy of XeF2 and wrote:

enter image description here

Then C. A. Coulson published The nature of the bonding in xenon fluorides and related molecules J. Chem. Soc., 1964, 1442-1454, which considered the validity of four models (plus some sub-models) of XeF2 bonding.

Coulson adds more resonance structures in addition to the two mentioned by Smith, including a purely ionic F- Xe2+ F- resonance structure.

For a more recent article on the topic, see The essential role of charge-shift bonding in hypervalent prototype XeF2 Nature Chemistry 5, 417–422 (2013). (official link)

Overall, ionic contributions do need to be considered.

deleted 4 characters in body
Source Link
DavePhD
  • 41k
  • 2
  • 91
  • 189

Just after XeF2 was discovered, D. F. Smith published a short communication Xenon Difluoride J. Chem. Phys. 38, 270 (1963) mentioning the electronic structure of your second drawing.

Smith conducted infrared spectroscopy of XeF2 and wrote:

enter image description here

Then C. A. Coulson published The nature of the bonding in xenon fluorides and related molecules J. Chem. Soc., 1964, 1442-1454, which was considered the validity of four models (plus some sub-models) of XeF2 bonding.

Coulson adds more resonance structure in addition to the two mentioned by Smith, including a purely ionic F- Xe2+ F- resonance structure.

For a more recent article on the topic, see TheThe essential role of charge-shift bonding in hypervalent prototype XeF2 Nature Chemistry 5, 417–422 (2013). (official link)

Overall, ionic contributions do need to be considered.

Just after XeF2 was discovered, D. F. Smith published a short communication Xenon Difluoride J. Chem. Phys. 38, 270 (1963) mentioning the electronic structure of your second drawing.

Smith conducted infrared spectroscopy of XeF2 and wrote:

enter image description here

Then C. A. Coulson published The nature of the bonding in xenon fluorides and related molecules J. Chem. Soc., 1964, 1442-1454, which was considered the validity of four models (plus some sub-models) of XeF2 bonding.

Coulson adds more resonance structure in addition to the two mentioned by Smith, including a purely ionic F- Xe2+ F- resonance structure.

For a more recent article on the topic, see The essential role of charge-shift bonding in hypervalent prototype XeF2 Nature Chemistry 5, 417–422 (2013).

Overall, ionic contributions do need to be considered.

Just after XeF2 was discovered, D. F. Smith published a short communication Xenon Difluoride J. Chem. Phys. 38, 270 (1963) mentioning the electronic structure of your second drawing.

Smith conducted infrared spectroscopy of XeF2 and wrote:

enter image description here

Then C. A. Coulson published The nature of the bonding in xenon fluorides and related molecules J. Chem. Soc., 1964, 1442-1454, which considered the validity of four models (plus some sub-models) of XeF2 bonding.

Coulson adds more resonance structure in addition to the two mentioned by Smith, including a purely ionic F- Xe2+ F- resonance structure.

For a more recent article on the topic, see The essential role of charge-shift bonding in hypervalent prototype XeF2 Nature Chemistry 5, 417–422 (2013). (official link)

Overall, ionic contributions do need to be considered.

Source Link
DavePhD
  • 41k
  • 2
  • 91
  • 189

Just after XeF2 was discovered, D. F. Smith published a short communication Xenon Difluoride J. Chem. Phys. 38, 270 (1963) mentioning the electronic structure of your second drawing.

Smith conducted infrared spectroscopy of XeF2 and wrote:

enter image description here

Then C. A. Coulson published The nature of the bonding in xenon fluorides and related molecules J. Chem. Soc., 1964, 1442-1454, which was considered the validity of four models (plus some sub-models) of XeF2 bonding.

Coulson adds more resonance structure in addition to the two mentioned by Smith, including a purely ionic F- Xe2+ F- resonance structure.

For a more recent article on the topic, see The essential role of charge-shift bonding in hypervalent prototype XeF2 Nature Chemistry 5, 417–422 (2013).

Overall, ionic contributions do need to be considered.