Timeline for Hydrogen peroxide generation by UV-Light
Current License: CC BY-SA 4.0
3 events
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Oct 8, 2022 at 22:42 | comment | added | jimchmst | I must apologize for using spontaneous in the vernacular sense because the production of the peroxide is spontaneous in the thermodynamic sense, otherwise it would not form. The energy supplied from imposed KE in the atomization overcomes the probably positive entropy change of a system far from equilibrium since there was no peroxide to start. All that is needed is a possible mechanism and the micro surfaces seem to provide that. Static electricity can be formidable albeit difficult to control and direct. | |
Oct 6, 2022 at 21:31 | comment | added | jimchmst | Nothing spontaneous about it; the atomization forms static electricity, think thunderstorm. here is their comment "In what follows, we report the direct, spontaneous generation of H2O2 from aqueous microdroplets in the absence of applied voltage, catalyst, or any other added chemicals. We also speculate about the nature of the mechanism responsible for these observations." I get upset when a proper energy balance is ignored; someone has to squeeze the rubber bulb. The chemistry is exciting tho. | |
Oct 6, 2022 at 13:02 | history | answered | ACR | CC BY-SA 4.0 |