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Timeline for Nitrogen dioxide dimerization

Current License: CC BY-SA 3.0

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Aug 16, 2014 at 14:01 vote accept EJC
Aug 16, 2014 at 13:49 comment added ron Good question! Remember that NO only dimerizes at low temperatures. Apparently molecular oxygen does similar things. Since molecular oxygen has 2 unpaired electrons, maybe we would expect a polymer or a cyclic oligomer? It turns out that one form of solid oxygen actually exists as $\ce{O_8}$. Read about "red oxygen" or $\ce{O_8}$ in this Wikipedia article en.wikipedia.org/wiki/Solid_oxygen#Red_oxygen Here's a link to an article where $\ce{O_4}$ is reported onlinelibrary.wiley.com/doi/10.1002/…
Aug 16, 2014 at 8:46 comment added EJC Why doesn't oxygen for a dimer then?
Aug 15, 2014 at 22:25 history answered ron CC BY-SA 3.0