# Tag Info

2

In acidic medium the equation must mention somewhere that some $\ce{H+}$ ions appear somewhere in the equation. In basic medium, the equation must mention somewhere that some $\ce{OH-}$ ions appear somewhere in the equation, For example, you may say that permanganate ion reacts in acidic conditions to produce $\ce{Mn^2+}$. In basic conditions, it could not ...

2

Copper(III) nitrate cannot be obtained from aqueous nitric acid, and likely doesn't exist. Reaction carried under strongly oxidative conditions between $\ce{Cu(NO3)2}$ and fuming $\ce{HNO3}$ yields in nitrosyl copper(II) trinitrate $\ce{[NO+][Cu(NO3)3−]},$ [1, 2] sometimes written as adduct $\ce{Cu(NO3)2 · N2O4},$ which is contradictory to the crystal ...

1

Say we have a given redox reaction: $$\ce{MnO4- + Fe^2+ -> Fe^3+ + Products}$$ This is an unbalanced redox reaction, just depicting how $\ce{Fe^2+}$ is oxidized to $\ce{Fe^3+}$ by $\ce{KMnO4}$. Now, depending on the medium, the following reactions may take place: In an acidic medium, $\ce{MnO4-}$ is reduced to $\ce{Mn^2+}$ by accepting 5 electrons \ce{...

1

If you consider the oxidation states of chlorine and oxygen, oxygen is REDUCING the chlorine as it goes from +5 to -1 (oxygen in turn is OXIDISED from -2 to 0). This makes no sense as O is more electronegative than Cl and I can only assume that since the reaction requires heat, this energy is driving a non-spontaneous reaction.

Only top voted, non community-wiki answers of a minimum length are eligible