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You seem unsure about the homolysis between C1 and C2, but I speculate to consider the product's stability in this suggested reaction: For one, two previously unpaired electrons form a $\pi$ bond in acetone. For the other, you form a benzyl radical which may be described in more than one mesomeric form, for example for a radical bromination reaction of ...


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Here is a rather simple structure explanation presented on this site. To quote, where 'pieces' refer to an organic molecular with a non-symmetric branching structure: You’ll notice something – the simpler the pieces are, the easier they are to stack together, which provides a tighter fit with fewer spaces. Here, by putting a kink in the block, we make ...


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