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Aminoxyl (trivial name: a nitroxyl radical or a nitroxide) denotes a radical functional group with general structure $\ce{R2N–O^•}$. It is well known that sterically unhindered aminoxyls baring $\alpha$‐hydrogens are unstable and undergo rapid disproportionation to nitrones and hydroxylamines (Ref.1: A new mechanism for the decomposition of $\alpha$‐hydrogen ...

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