# Tag Info

3

Brønsted Acid has been used in Friedel-Crafts alkylation before (for example, Ref.1). According to this reference, when toluene use as the solvent (), the F-C alkylation reaction of toluene is fruitful for tertiary and secondary alkyl bromides, tosylates, and alkenes (which give both carbocations upon protonation). However, the only primary bromide, which ...

3

These would be the arguments I propose under the assumption that the RDS approximation is valid within the scope of the question: The order (B > A > C > D) was said to be correct for the conc. $\ce{H2SO4}$/ $\Delta$ case since there would be no effect of $\ce{CH-}$ acidity since the protonation of the $\ce{-OH}$ group takes place and so the ...

1

An acid catalysed dehydration reaction of alcohols will always proceed with the removal of -OH as H2O molecule and therefore, will be dependent on the formed carbocation's stability because the rate deternining step for this process is formation of carbocation. Carbocation Carbocation can be stabilized by inductive effect, field effect, mesomeric effect (or) ...

2

Your basic assumptions are correct. It can be observed as such: In Q the carbocation is stablised by resonance, inductive and hyperconjugative effects so it is quite stable and will be formed fastest. Comparing P and R: In P, a secondary carbocation is formed and there are 4+1 or 5 hyperconjugative structures possible. Moreover, the inductive effect is also ...

7

The answer varies slightly depending on whether the migration is one-step or two-step via an intermediate. In either case, the respective transition state or intermediate looks like this: You can see that the middle structure would be stabilized most by a group that is able to stabilize the ring via resonance, for example, an alkoxy substituent. If the ...

7

I think the third option as greatest number of resonance structures can be alluded to it. The following may suffice: In the first one, the carbocation is isolated except for the presence of a single double bond in conjugation beside it. The oxygen and the double bond beside it play no role in stablizing it. In the second one the lone pair on oxygen, the ...

4

Your answer is the correct one. Acid-catalysed hydrolysis of epoxides proceeds exactly as shown. In the specific case of styrene oxide, nucleophiles attach themselves to the benzylic carbon1,2, which means that A should be the major product. I'm attaching an image from (1) which gives the products of reaction of methanol with styrene oxide: If you want to, ...

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