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Search options not deleted user 99732

This tag should be applied to questions that deal with the particular arrangement of atoms in a molecule, the so-called molecular structure or geometry.

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How do the spin-matrices change in systems without spherical symmetry?

The (non-relativistic) spin matrices of a free electron, with $z$ as the quantization axis, read: $$ \boldsymbol{S}_{x}=\frac{\hbar}{2}\left[\begin{array}{ll} 0 & 1 \\ 1 & 0 \end{array}\right], \quad …