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Use of molecular orbital (MO) theory allows for an understanding of the observed properties (shape, reactivity) of molecules. The tag should be applied to all questions related to MO theory, from questions about the qualitative use of the theory to questions about the underlying quantum mechanics and applications in computational chemistry.
3
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Can pi backdonation occur on non-metal centers?
Yes.
This is a hot topic in main group chemistry, and has been used to explain stable CO complexes with main group elements.
Here is a very nice open-access article by Sergeieva et al. where they look …