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Applicable to questions about heat, energy, work, and their interconversion in chemistry. See the tag wiki for a detailed list of topics. Questions tagged may also be tagged with [enthalpy], [energy], [free-energy] where appropriate.

4 votes
2 answers
2k views

Why is the value of "a" is positive instead of negative in Van der Waals equation?

Higher value of a means higher atttraction force between molecules. Attraction force causes the pressure to be less than expected. Now the actual pressure becomes $P + \frac{n^2a}{V^2}$ . Which means …
Farhan Fuad's user avatar