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For questions relating to the electronic structure of inorganic complexes, particularly the splitting of degenerate $d$ or $f$ orbitals by the symmetry of the surrounding ligands.
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Transition of electrons between t2g and eg to give colour of coordination compounds
So, how the electrons will transfer from the t2g orbitals to any higher filled orbital?
This concept of t2g and eg comes in crystal field theory.
According to NCERT chemistry class 12 it is written …
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Colour of coordination compounds due to d-d transition
Hexaaquanickel(II) is green but tetracyanidonickelate(II) is colourless.
On internet I found two explanations.
One used valence bond theory that claimed there is no excitation of electron in tetracya …