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For questions about the thermodynamical state function entropy, commonly understood as a measure of disorder.

2 votes
1 answer
152 views

Question about entropy generated in isothermal expansion of an ideal gas

The total change in entropy is given by $$\mathrm dS_\text{total}=\mathrm dS_\mathrm{system}+\mathrm dS_\mathrm{surroundings}$$ Now, the entropy change for the system is $$\mathrm dS_\mathrm{system}=\mathrm … dS_\mathrm{produced}+\mathrm dS_\mathrm{exchanged}$$ where, $\mathrm dS_\mathrm{produced}$ is internally produced entropy in the system and $\mathrm dS_\mathrm{exchanged}$ is entropy change due to exchange …
Natasha J's user avatar
  • 305
2 votes
1 answer
178 views

What processes generate entropy as heat flows across temperature gradient

If $Q_\mathrm h$ amount of heat flow from source to sink, then change in entropy of source is $\frac{-Q_\mathrm h}{T_\mathrm h}$ and change in entropy of sink is $\frac{+Q_\mathrm h}{T_\mathrm l}$. … And while I understand that entropy is being generated in the partition, my question is how does heat conduction across a finite temperature gradient generates entropy
Natasha J's user avatar
  • 305
0 votes
0 answers
175 views

Why is work done on the system in irreversible adiabatic compression greater than work done ...

When one of the weights is reduced( for expansion), the pressure on the piston drops suddenly and the piston shoots up, so there will be temperature gradients inside the gas, which will give rise to entropy
Natasha J's user avatar
  • 305
0 votes
1 answer
75 views

Entropy of the system is different for irreversible and reversible adiabatic process?

Entropy change of a system is a state function... … Shouldn't the entropy of the system in both cases must be same? This answer: How would one calculate the entropy change for an adiabatic irreversible process? …
Natasha J's user avatar
  • 305
-1 votes
1 answer
281 views

How do I find entropy change for surroundings?

I know how to calculate entropy change of the system but am not able to calculate entropy change for surroundings. … I was able to calculate the entropy change of system. It came out to be, $\Delta S_{sys} = 123JK^{-1}mol^{-1}$. But I am stuck at change in entropy of surroundings. …
Natasha J's user avatar
  • 305