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The study of chemical systems using the laws and concepts of physics. This usually requires the techniques of thermodynamics, statistical mechanics and quantum mechanics.

3 votes
2 answers
140 views

Can we calculate van der Waals' constant a for the following case?

The given Z vs P curve for 1 mole of a gas at 400K starts at Z=1 & P=0. The slope at the point when the curve again intersect Z=1 is 0.005. The critical temperature of the gas is 500K. My approach: F …
Leibniz-Z's user avatar
  • 208
2 votes
1 answer
89 views

Why is the work done on the system not equal in frame of gas and surroundings?

Consider an isothermal irreversible process for an ideal gas in a cylindrical container closed with a piston (system). Initial and final states are $(P_1,V_1,T)$ and $(P_2,V_2,T)$ respectively. Initia …
Leibniz-Z's user avatar
  • 208