For the reaction. $$\ce{M -> M+ +e-}$$ The heat liberated is highest for lithium owing to its high negative $E°$ value so one would think that the reaction must be most vigorous. The reason behind the more violent reactivity of potassium rather than lithium lies in **kinetics** not thermodynamics. No doubt, maximum energy is evolved with lithium but the vaporization and and ionization will also consume maximum energy ( m.pt and I.E of lithium are the highest) and so the reaction proceeds gently. On the other hand potassium has a lower melting point And the ionization enthalpy . The heat of reaction is sufficient to make them melt. The molten metal spreads over the water and exposes a larger surface to water . Also the hydrated radius of lithium is the greatest out of all alkali metal. This reduces the ionic mobility. Which in turn reduces the speed of the molten metal . That's why potassium gives a more violent reaction with water. *** **SOURCE** Conceptual Inorganic Chemistry; Prabhat Kumar