Questions tagged [temperature]

A measure of the average kinetic energy of the particles in a sample of matter; may be expressed either in kelvin (symbol K) or in degree Celsius (symbol °C).

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Is there a structured data source containing information on the World Health Organisation's Stability Testing Policies?

Hoping to automate some product testing guidance software, I've been attempting to find a (hopefully live, up-to-date) Database, Web-service, or other structured data source containing the ...
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356 views

How would you measure the rate of this SN1 reaction?

I am performing the following $\mathrm{S_N1}$ reaction: $$\ce{t-BuOH + HCl -> t-BuCl + H2O}$$ I would also like to measure the rate of this reaction, but I cannot seem to find a way. I initially ...
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Can this happen to superheated water?

Superheated water refers to water that is heating well beyond its usual boiling point under extreme pressure. This cause it to display anomalous property. I noticed that as temperature increases, so ...
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Can 0-Carborane be stored at room temperature?

I am a physics post-doc at Oak Ridge National Lab (with a bit more training in chem than the average physicist). I ordered a small sample of o-Carborane from Sigma-Aldrich to test for doping liquid ...
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A formula for the refractive index of a gas dependent on temperature and pressure

I am in search for a formula that gives me the refractive index of a gas at a given temperature and pressure. Does such a formula exist? Ideally the solution should have this form: $n_g(t, p) = \...
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When is a reaction feasible at room temperature?

Gibbs free energy determines whether a reaction will occur spontaneously or not. Still, the activation barrier of a reaction determines if a reaction will occur at a given temperature. At any non-zero ...
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How could I find the solubility of hydrocarbons such as iso- and n-Butane in liquid Methane?

I am trying to figure out the dissolution capacity of iso and normal butane in methane at very low temperatures (110K). This would allow me to make compositions that prevent freeze out of these ...
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Target temperature for infused cooking oil

A little context: I make craft chili oils for friends and family. I use a two-step infusion process. First, I infuse the oil for flavor by simmering spices in the oil held around 250 degrees ...
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339 views

Why is temperature considered as an important factor in deciding chemical reaction kinetics?

According to the Arrhenius equation, the rate of reaction is proportional to $e^{-1/RT}$. Here is a plot of the equation and its derivative with respect to temperature, both with respect to ...
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Heat capacity during state change

I read that the heat capacity of water when it is at 100 °C or 0 °C is infinite because all the heat given to it will not be used to increase temperature but to change the state. I am unable to ...
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What is the explanation of the odd even effect in liquid crystals?

What is the most accepted theory for explaining the odd even effect in liquid crystals? Can anyone explain and refer the corresponding paper?
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591 views

heat capacity and thermal equilibrium

A $52\ \mathrm{g}$ piece of iron at $250\ \mathrm{^\circ C}$ is added to a mixture of $100\ \mathrm{g}$ of ice and $100\ \mathrm{g}$ of liquid water at thermal equilibrium $(0\ \mathrm{^\circ C})$. ...
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Arrhenius equation using concentration

I've been conducting some experiments to determine the temperature dependence of a reaction. To do this, I've been conducting the experiments at different temperatures and generated a graph of $\ln{[\...
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Gas Law - increasing temperature with constant volume held

I've set up a simple experiment to look at the ideal gas laws. My experiment is relatively simple in that I have a metal tube which is capped on one side. I am then pressurising the tube with air to ...
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Derive expression for average heat flux in heat exchanger

The single-tube heat exchanger is used to increase the temperature of fluid I from $T_{b1}$ to $T_{b2}$. The heating oil (fluid II) used for this task enters at temperature $T_{02}$ and leaves at ...
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Freezing point lowering for a mixture of many liquids

I have been taught that if I have a solute of molality $m$ mixed with a liquid, the freezing point in lowered by an amount $K_\mathrm{f}\cdot m$ where $K_\mathrm{f}$ is the molal freezing depression ...
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Why do higher intermolecular forces lead to a higher change in temperature?

We performed an experiment in chemistry where tissue paper soaked in various chemicals was wrapped around the end of a temperature probe. The chemicals with stronger intermolecular forces had a lower ...
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How does Boudouard reaction influence the temperature?

I've a question that is giving me a lot of troubles: I'm depositing and gasifying Carbon by varying a flow rate of $\ce{CO}$ and $\ce{CO2}$ and by using the Boudouard reaction ($\ce{2CO -> C + CO}$)...
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Up to which temperature and pressure can dendrimers (PAMAM) be stable?

I am preparing PAMAM (poly amido-amine) dendrimer and I want to know up to which temperature and pressure can it be stable?
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Determining the acid dissociation constant change with temperature in sparkling water

I already have the different values of pH at the different temperatures, but what I'm trying to figure out is obtaining the acid dissociation constant using these pH values. Is there a way I can do ...
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How to evaluate enthalpy variation of combustion of sucrose in a constant volume calorimeter?

Consider combustion reaction (with the formation of $H_2O$ and $CO_2$) of a mass $m$ of sucrose in a constant volume calorimeter with thermal capacity $C$. This reaction increases the temperature of $...
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62 views

Silicone with good thermal conductivity

I am looking for a material with the same properties of silicone (flexible, easy to manipulate, soft, etc.) but without being a thermal isolate. I need this material to do the junction between a ...
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How to determine parameters range?

I am into running some leaching experiments and wanted to study the effect of different parameters on my dissolution results. But I am confused with determining the parameters range. For example, I ...
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Reaction rate in terms of temperature change

For exothermic reaction where concentration changed in hard to measure, can I interpret the rate of reaction in terms of temperature change? For example, if the experiment is iron rusting reaction ...
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Metaphosphoric acid and water in cold

Consider this redox reaction: $$\ce{3PCl3 + 2HNO3 (conc.) + 5H2O → 2NO + 3[HPO3] + 9HCl}$$ The metaphosphoric acid is taken in square brackets, because I have doubts about it. As I know, this ...
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Parameter effects on kinetics of esterification for bio-diesel production

I want to discuss the effect of parameters on the kinetics of esterification for bio-diesel production. In esterification process, temperature effect and molar ration are two important parameters. ...
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Entropy as “extent of energy dispersal” vs. entropy as defined by the Clausius equation

Currently, the concept of entropy as "energy dispersal" has been proved to be more easy to understand than the concept of "disorder". While the first can be applied successfully to explain the ...
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What is the temperature at which lava evaporates?

According to this article -> http://ntrs.nasa.gov/search.jsp?R=19660041998 Lava evaporates under natural conditions, but apparently, only a little bit. I'd like to know the temperature at which ...
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Why does melting point depend on external pressure?

The melting point of a substance is the temperature at which the solid form's vapor pressure equals the liquid form's vapor pressure. I read that the vapor pressure of something depends ONLY on the ...
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Why does the Temperature Decrease?

This is from a calorimetry lab. $50\ \mathrm{ml}$ of acid and base were mixed. Why does the temperature keep decreasing after 1 minute and why isn't at a constant rate? Is it because heat is lost to ...
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Does freezing tights make them more durable?

Various blog posts and articles suggest that freezing a pair of tights will make them last longer. From a blog named Eclipsed Moon: Put your tights in the freezer. I thought that this was ...
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How can I use sunlight to heat a RBF and reflux a reaction?

This may seem like a off topic question but I really need help on it. I am currently working on a polymerization reaction in which I'm breaking down plastic polymers into smaller molecules. However, ...
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Melting temperature vs Isotropisation temperature in liquid crystals

What is exactly the difference between these two? I think melting point is when the compound melts down to visually liquid state but actually LC state and latter is when polymer becomes completely ...
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What is the equation that demonstrates the relationship between molar conductivity and temperature?

Can someone please help me find the equation that defines the relation between molar conductivity and temperature. I have found some information, but it was not really that much complete.
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How to calculate the temperature change when CaCl2, NaCl, and water added together at an initial temperature of 298 K?

My question: How to calculate the temperature change when adding $\pu{0.1 kg}$ of $\ce{CaCl2}$ and $\pu{0.1 kg}$ of $\ce{NaCl}$ to $\pu{1 kg}$ water with an initial temperature of $\pu{298 K}$? I ...
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Why doesn't a temperature and pressure gradient exist in a container of real gas?

In the Kinetic theory of gases, it is assumed that there are no intermolecular forces between the atoms/molecules. But real gases, have intermolecular attractive and repulsive forces. Suppose a ...
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What causes mercury to expand equaly unregarded what the temperature increase is?

Mercury seemed to be a good liquid to use in thermometers. But why are most liquids expanding non-linearly with increase of temperature compared to other liquids?
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Can I freeze water at 100 °C if I add 28 grams NaCl in 100 grams water?

Can I freeze water at 100 °C if I add 28 grams NaCl in 100 grams water at 20 °C? I found this diagram that says, if I have 28.05 wt% NaCl in water, then the equilibrium temperature between two phases ...
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High temperature acids

Some of the proton production of an acid happens due to temperature and some of the proton production of an acid happens due to quantum tunnelling.But if we increase the temperature a lot the proton ...